Metal Hydroxides

Chemistry: AQA GCSE Higher, topic 8.3.3

Metal Hydroxides - Calcium, Magnesium and Aluminium

Metal ions can be found in aqueous solutions of metal compounds. These ions can precipitate out of solution when they react with a sodium hydroxide solution (NaOH). This produces insoluble solids (don't dissolve in water) called precipitates.

Calcium hydroxide

Calcium hydroxide

  • Calcium ions (Ca2+) form the white precipitate calcium hydroxide.
  • Ca2+(aq) + 2OH-(aq) → Ca(OH)2(s)
Magnesium hydroxide

Magnesium hydroxide

  • Magnesium ions (Mg2+) form the white precipitate magnesium hydroxide.
  • Mg2+(aq) + 2OH-(aq) → Mg(OH)2(s)
Aluminium hydroxide

Aluminium hydroxide

  • Aluminium ions (Al3+) form the white precipitate aluminium hydroxide.
  • Al3+(aq) + 3OH-(aq) → Al(OH)3(s)
  • Unlike the other two white precipitates, aluminium hydroxide can be dissolved in excess NaOH. This produces a colourless solution.

Test yourself on Metal Hydroxides

  • Which metal ion must be present if a white precipitate forms with sodium hydroxide solution and then dissolves when excess sodium hydroxide is added?

  • What are the correct colours for the following precipitates?

  • Which equation correctly represents magnesium ions reacting with hydroxide ions to form magnesium hydroxide?

  • Why does the equation for aluminium hydroxide formation need 3 hydroxide ions, while the equations for calcium and magnesium hydroxide only need 2?

  • What does the state symbol (s) show about calcium hydroxide in the equation Ca2+(aq) + 2OH-(aq) → Ca(OH)2(s)?

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