Empirical Formulae
Chemistry: AQA GCSE Higher, topic 2.1.5
Empirical Formulae
You can work out the proportion of each ion in a compound. The empirical formula of an ionic compound is the simplest ratio of ions possible.

Ca2+ and F-
- In order for the charges to balance out and for the overall formula to be neutral, there must be 2 F- ions for each Ca2+ ion.
- The empirical formula is CaF2
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Na+ + SO42-
- In order for the charges to balance out and for the overall formula to be neutral, there must be 2 Na+ ions for each SO42- ion.
- The empirical formula is Na2SO4.
Test yourself on Empirical Formulae
If an ionic compound contained Mg2+ and O2- ions, what would the empirical formula be?
Which of the following is the correct empirical formula?
What are the three steps used to work out the empirical formula of an ionic compound?
If a compound contained Ca2+ ions and Cl- ions, what would the empirical formula be?