Chemical Properties of Small Molecules

Chemistry: AQA GCSE Higher, topic 2.3.4

Intermolecular Forces and Molecule Structure

The size of a molecule affects the overall strength of intermolecular forces. The strength of intermolecular forces affects the properties of a molecule.

Small molecules

Small molecules

  • Small molecules have weak intermolecular forces. This means that small molecules have low melting and boiling points.
  • Because of this, they are often liquids or gases at room temperature.
  • Small molecules don't contain delocalised electrons.
  • Because of this, they cannot conduct electricity.
Chlorine - example of a small molecule

Chlorine - example of a small molecule

  • Cl2 (the diatomic molecule of chlorine) is a small molecule with weak intermolecular forces between its molecules.
  • Chlorine is a gas at room temperature.
Bigger molecules

Bigger molecules

  • Bigger molecules attract other molecules with stronger intermolecular forces. This means that they have higher melting and boiling points than small molecules.
  • Bigger molecules don't contain delocalised electrons, and so can't conduct electricity.
Sucrose - example of a bigger molecule

Sucrose - example of a bigger molecule

  • Sucrose is made of 45 atoms and has the formula C12H22O11.
  • Although sucrose is a simple molecule, its size means that its intermolecular forces are strong enough for it to be solid at room temperature.

Test yourself on Chemical Properties of Small Molecules

  • Which molecule has higher melting and boiling points?

  • Why is chlorine a gas at room temperature?

  • Why do bigger molecules have stronger overall intermolecular forces than smaller molecules?

  • Which statement about molecules at room temperature is correct?

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