NPK Fertilisers - P-containing Compound

Chemistry: AQA GCSE Higher, topic 10.4.8

Phosphorus-Containing Compounds in Fertilisers

Phosphate rock is a source of insoluble phosphorus that is obtained by mining. Useful soluble products can be obtained by treating the rock with acids:

Phosphate rock + nitric acid

Phosphate rock + nitric acid

  • Phosphate rock + nitric acid → phosphoric acid + calcium nitrate
Phosphate rock + sulfuric acid

Phosphate rock + sulfuric acid

  • Phosphate rock + sulfuric acid → single superphosphate
  • Single superphosphate is a mixture of calcium sulfate and calcium phosphate.
Phosphate rock + phosphoric acid

Phosphate rock + phosphoric acid

  • Phosphate rock + phosphoric acid → triple superphosphate
  • Triple superphosphate is also known as calcium phosphate.

Test yourself on NPK Fertilisers - P-containing Compound

  • Why is phosphate rock treated with acids before it is used in fertilisers?

  • Triple superphosphate, made from phosphate rock and phosphoric acid, is a single calcium compound. Single superphosphate, made from phosphate rock and sulfuric acid, is a mixture of two calcium compounds. Name these two compounds.

  • How does the reaction between phosphate rock and nitric acid differ from the reaction between phosphate rock and sulfuric acid?

  • How does the composition of single superphosphate differ from the composition of triple superphosphate?

  • Phosphate rock reacts with nitric acid to produce phosphoric acid and calcium nitrate. If this phosphoric acid is then reacted with more phosphate rock, what product forms?

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