Molecular Kinetic Theory Model 2

Test yourself

Average molecular kinetic energy

The average molecular energy can be used to find the pressure of radiation.

Kinetic energy

We assume that a gas is homogeneous (the same everywhere) and isotropic (has the same value when measured in different directions).
This means that the average speed of a molecule in the x-direction must be the same as the y and the z-directions. So we can write:
- ${v_x}={v_y}={v_Z}$
This means that the average kinetic energy in each direction is the same.

Momentum

We consider a cube of length l which contains a gas.
If we only look at the x-direction, we can say that the time taken for a particle to travel from one end to the other is:
- $t=\frac{l}{{v_x}}$
If a particle collides with the wall of the box and is absorbed, we can write the change in momentum as:
- Change in momentum = mass x velocity
- $P=m{v_x}$

Force

We can write the force exerted on the wall when it absorbs a particle as:
- Force = change in momentum ÷ change in time
- $F=\frac{P}{t}$
We can substitute in the equations for momentum and time to get:
- $F=\frac{m{v_x}^2}{l}$

Pressure

The pressure on the wall of the box when it absorbs one particle is given by the equation:
- Pressure = force ÷ area
- $p=\frac{F}{A}$
We can use the value for force and that the area is length squared to get:
- $p=\frac{m{v_x}^2}{l^3}$
Since volume is length cubed we get:
- $p=\frac{m{v_x}^2}{V}$

Pressure 2

We have found the pressure for one particle if N particles hit the wall the pressure would be:
- Total pressure = number of particles x pressure from one particle.
- ${p_t}=Np$
We can substitute the pressure in to give:
- ${p_t}=N\frac{m{v_x}^2}{V}$

Kinetic equation

Recalling that the velocity is the same in all directions, we can write an equation for the total velocity squared as:
- ${v_t}^2= {v_x}^2+{v_y}^2+{v_z}^2$
Because the velocities are equal, we can simplify to give:
- ${v_x}^2=\frac{1}{3}{v_t}^2$
So the equation for pressure can be written as:
- $pV=\frac{1}{3}Nmv^2$

Molecular Kinetic Theory - Developments Over Time

Ideas about the underlying structure of materials have changed considerably over time.

Early ideas

The idea that the atom, or atoms that are too small to directly view, move around is ancient. This dates from Lucretius in approx 50 BCE.
This idea was largely ignored because of the predominance of Aristotelian ideas about elements such as fire, earth, air and water.

Particle nature of matter

The modern theory of the particle nature of matter was attributed to Bernoulli.
This was prior to the ideas of conservation of energy and how collisions between particles could be elastic.
The model did not predict anything in itself.

More complex ideas

Clausius developed a much more complex set of ideas.
The observation of Brownian motion is the first direct evidence of the existence of particles.
The kinetic theory of gases became universally accepted because of Einstein and Smoluchowski’s theoretical model, which made specific predictions about Brownian motion and diffusion.

1Measurements & Errors

1.1Measurements & Errors

1.1.1Use of SI Units

1.1.2SI Prefixes, Standard Form & Converting Units

1.1.3End of Topic Test - Units & Prefixes

1.1.4Limitation of Physical Measurements

1.1.5Uncertainty

1.1.6Estimation

1.1.7End of Topic Test - Measurements & Errors

2Particles & Radiation

2.1Particles

2.1.1Atomic Model

2.1.2Specific Charge, Protons & Neutron Numbers

2.1.3End of Topic Test - Atomic Model

2.1.4Isotopes

2.1.5Stable & Unstable Nuclei

2.1.6End of Topic Test - Isotopes & Nuclei

2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei

2.1.8Particles, Antiparticles & Photons

2.1.9Particle Interactions

2.1.10Classification of Particles

2.1.11End of Topic Test - Particles & Interactions

2.1.12Quarks & Antiquarks

2.1.13Application of Conservation Laws

2.1.14End of Topic Test - Leptons & Quarks

2.1.15Exam-Style Question - Radioactive Decay

2.2Electromagnetic Radiation & Quantum Phenomena

2.2.1The Photoelectric Effect

2.2.2The Photoelectric Effect Explanation

2.2.3End of Topic Test - The Photoelectric Effect

2.2.4Collisions of Electrons with Atoms

2.2.5Energy Levels & Photon Emission

2.2.6Wave-Particle Duality

2.2.7End of Topic Test - Absorption & Emission

3Waves

3.1Progressive & Stationary Waves

3.1.1Progressive Waves

3.1.2Wave Speed & Phase Difference

3.1.3Longitudinal & Transverse Waves

3.1.4End of Topic Test - Progressive Waves

3.1.5Polarisation

3.1.6Stationary Waves

3.1.7Stationary Waves 2

3.1.8End of Topic Test - Polarisation & Stationary Wave

3.1.9A-A* (AO3/4) - Stationary Waves

3.2Refraction, Diffraction & Interference

3.2.1Interference

3.2.2Interference 2

3.2.3End of Topic Test - Interference

3.2.4Diffraction

3.2.5Diffraction Gratings

3.2.6End of Topic Test - Diffraction

3.2.7Refraction at a Plane Surface

3.2.8Internal Reflection & Fibre Optics

3.2.9End of Topic Test - Refraction

3.2.10Exam-Style Question - Waves

4Mechanics & Materials

4.1Force, Energy & Momentum

4.2Materials

4.2.1Density

4.2.2Bulk Properties of Solids

4.2.3Energy in Materials

4.2.4Young Modulus

4.2.5End of Topic Test - Materials

5Electricity

5.1Current Electricity

5.1.1Basics of Electricity

5.1.2Current-Voltage Characteristics

5.1.3End of Topic Test - Basics of Electricity

5.1.4Resistivity

5.1.5Superconductivity

5.1.6A-A* (AO3/4) - Superconductivity

5.1.7End of Topic Test - Resistivity & Superconductors

5.1.8Circuits

5.1.9Power and Conservation

5.1.10Potential Divider

5.1.11Emf & Internal Resistance

5.1.12End of Topic Test - Power & Potential

5.1.13Exam-Style Question - Resistance

6Further Mechanics & Thermal Physics (A2 only)

6.1Periodic Motion (A2 only)

6.1.1Circular Motion

6.1.2Circular Motion 2

6.1.3End of Topic Test - Circular Motion

6.1.4Simple Harmonic Motion

6.1.5Simple Harmonic Systems

6.1.6Energy in Simple Harmonic Motion

6.1.7Resonance

6.1.8End of Topic Test - Simple Harmonic Motion

6.1.9A-A* (AO3/4) - Simple Harmonic Motion

6.2Thermal Physics (A2 only)

6.2.1Thermal Energy Transfer

6.2.2Thermal Energy Transfer Experiments

6.2.3Ideal Gases

6.2.4Ideal Gases 2

6.2.5Boyle's Law & Charles' Law

6.2.6Molecular Kinetic Theory Model

6.2.7Molecular Kinetic Theory Model 2

6.2.8End of Topic Test - Thermal Energy & Ideal Gases

6.2.9Exam-Style Question - Ideal Gases

7Fields & Their Consequences (A2 only)

7.1Fields (A2 only)

7.1.1Fields

7.2Gravitational Fields (A2 only)

7.2.1Newton's Law

7.2.2Gravitational Field Strength

7.2.3Gravitational Potential

7.2.4Orbits of Planets & Satellites

7.2.5Escape Velocity & Synchronous Orbits

7.2.6End of Topic Test - Gravitational Fields

7.3Electric Fields (A2 only)

7.3.1Coulomb's Law

7.3.2Electric Field Strength

7.3.3Electric Field Strength 2

7.3.4Electric Potential

7.3.5End of Topic Test - Electric Fields

7.3.6A-A* (AO3/4) - Electric and Gravitational Field

7.4Capacitance (A2 only)

7.4.1Capacitance

7.4.2Parallel Plate Capacitor

7.4.3Energy Stored by a Capacitor

7.4.4Capacitor Discharge

7.4.5Capacitor Charge

7.5Magnetic Fields (A2 only)

7.5.1Magnetic Flux Density

7.5.2End of Topic Test - Capacitance & Flux Density

7.5.3Moving Charges in a Magnetic Field

7.5.4Magnetic Flux & Flux Linkage

7.5.5Electromagnetic Induction

7.5.6Electromagnetic Induction 2

7.5.7Alternating Currents

7.5.8Operation of a Transformer

7.5.9Magnetic Flux Density

7.5.10End of Topic Test - Electromagnetic Induction

8Nuclear Physics (A2 only)

8.1Radioactivity (A2 only)

8.1.1Rutherford Scattering

8.1.2Alpha & Beta Radiation

8.1.3Gamma Radiation

8.1.4Radioactive Decay

8.1.5Half Life

8.1.6End of Topic Test - Radioactivity

8.1.7Nuclear Instability

8.1.8Nuclear Radius

8.1.9Mass & Energy

8.1.10Binding Energy

8.1.11Induced Fission

8.1.12Safety Aspects of Nuclear Reactors

8.1.13End of Topic Test - Nuclear Physics

8.1.14A-A* (AO3/4) - Nuclear Fusion

9Option: Astrophysics (A2 only)

9.1Telescopes (A2 only)

9.1.1Astronomical Telescopes

9.1.2Reflecting Telescopes

9.1.3Single Dish Radio Telescopes

9.1.4Large Diameter Telescopes

9.2Classification of Stars (A2 only)

9.2.1Classification by Luminosity

9.2.2Absolute Magnitude

9.2.3Black Body Radiation

9.2.4Stellar Spectral Classes

9.2.5Hertzsprung-Russell Diagrams

9.2.6Astronomical Objects

9.3Cosmology (A2 only)

9.3.1Doppler Effect

9.3.2Hubble's Law

9.3.3Quasars

9.3.4Detecting Exoplanets

10Option: Medical Physics (A2 only)

10.1Physics of the Eye (A2 only)

10.1.1Physics of Vision

10.1.2Defects of Vision

10.1.3Lenses

10.1.4Correcting Defects of Vision

10.2Physics of the Ear (A2 only)

10.2.1Structure of the Ear

10.2.2Sensitivity of the Ear

10.2.3Hearing Defects

10.3Biological Measurement (A2 only)

10.3.1Electrocardiography (ECG)

10.4Non-Ionising Imaging (A2 only)

10.4.1Ultrasound Imaging

10.4.2Ultrasound Imaging 2

10.4.3Fibre Optics & Endoscopy

10.4.4Magnetic Resonance Scanning

10.5X-Ray Imaging (A2 only)

10.5.1Diagnostic X-Rays

10.5.2X-Ray Image Processing

10.5.3Absorption of X-Rays

10.5.4CT Scanners

10.6Radionuclide Imaging & Therapy (A2 only)

10.6.1Imaging Techniques

10.6.2Half Life

10.6.3Gamma Camera

10.6.4High Energy X-Rays

10.6.5Radioactive Implants

10.6.6Imaging Comparisons

11Option: Engineering Physics (A2 only)

11.1Rotational Dynamics (A2 only)

11.1.1Moment of Inertia

11.1.2Rotational Kinetic Energy

11.1.3Rotational Motion

11.1.4Torque & Angular Acceleration

11.1.5Angular Momentum

11.1.6Angular Work & Power

11.2Thermodynamics & Engines (A2 only)

11.2.1First Law of Thermodynamics

11.2.2Non-Flow Processes

11.2.3p-V Diagrams

11.2.4Engine Cycles

11.2.5Second Law & Engines

11.2.6Reversed Heat Engines

12Option: Turning Points in Physics (A2 only)

12.1Discovery of the Electron (A2 only)

12.1.1Cathode Rays

12.1.2Thermionic Electron Emission

12.1.3Electron Specific Charge

12.1.4Millikan's Experiment

12.2Wave-Particle Duality (A2 only)

12.2.1Newton's & Huygen's Theories of Light

12.2.2Electromagnetic Waves

12.2.3Photoelectricity

12.2.4Wave-Particle Duality

12.2.5Electron Microscopes

12.3Special Relativity (A2 only)

12.3.1Michelson-Morley Experiment

12.3.2Einstein's Theory of Special Relativity

12.3.3Time Dilation

12.3.4Length Contraction

12.3.5Mass & Energy

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