2.2.5
Energy Levels & Photon Emission
Energy Levels in Atoms
Energy Levels in Atoms
Electrons in atoms must occupy a discrete energy level.
Energy levels
Energy levels
- Electrons do not float around randomly in atoms.
- They can only be found at set energy levels.
- Each energy level is given a 'quantum number'.
- The ground state is the lowest energy level. The ground state has n = 1.
- The higher the energy level, the larger its quantum number, n.
Transitions between energy levels
Transitions between energy levels
- An electron can transition between energy levels by absorbing or emitting a photon of a specific frequency.
- If an electron emits a photon, it will drop an energy level.
- If an electron absorbs a photon, it will rise to a higher level.
- In both cases, the photon must have energy exactly equal to the energy difference between the levels.
Equation
Equation
- The movement of electrons between energy levels can be represented in the equation:
- This shows that the energy difference between levels one and two is equal to the energy of the emitted (or absorbed) photon.
Excitation and ionisation
Excitation and ionisation
- If an electron absorbs a photon and jumps up an energy level, we say it has been excited.
- If an electron absorbs a photon that is so energetic it is knocked out of the atom altogether, the electron has been ionised.
Absorption Spectra
Absorption Spectra
Electrons in atoms can only move between discrete energy levels. So an atom can only absorb or emit photons with particular frequencies (or wavelengths).
White light - continuous spectrum
White light - continuous spectrum
- White light contains all the colours in the visible part of the spectrum.
- When white light is passed through a prism or a diffraction grating, the colours are split up to produce a continuous spectrum.
- Continuous means there aren't any gaps or black lines.
Cool gas - absorption spectra
Cool gas - absorption spectra
- A cool gas means a gas containing atoms in their ground state.
- When white light is passed through a cool gas, electrons in the ground state of the atom absorb certain frequencies of light and become excited.
- Most frequencies of the white light are not absorbed because they do not correspond to the difference between two energy levels in the atom.
Absorption spectra 2
Absorption spectra 2
- If the light coming out of the cool gas is split by a prism (or diffraction grating), we see a continuous spectrum with black lines.
- These lines are called absorption lines.
- They are unique to each type of atom.
Emission Spectra
Emission Spectra
Electrons in atoms can only move between discrete energy levels. So an atom can only absorb or emit photons with particular frequencies (or wavelengths).
Excited gas
Excited gas
- An excited gas contains atoms in excited energy states.
- These excited atoms contain electrons in high energy levels.
- As these electrons de-excite and fall back to lower energy levels, photons are emitted.
Photon emission
Photon emission
- These photons carry away energy from the atoms.
- The amount of energy (and so what frequency) the photons have depends on the difference in energy levels in the atom.
- For every possible electron transition, there will be a unique frequency photon emitted.
- We see a series of bright lines when we pass the emitted light through a prism or diffraction grating.
Emission vs absorption
Emission vs absorption
- Compare the emission and absorption spectra produced by this gas.
- We can see that the emission lines exactly match the frequencies of the absorption lines.
- This is because the lines correspond to the same energy differences in the atoms. The same energy photons are either emitted or absorbed.
1Measurements & Errors
2Particles & Radiation
2.1Particles
2.1.1Atomic Model
2.1.2Specific Charge, Protons & Neutron Numbers
2.1.3End of Topic Test - Atomic Model
2.1.4Isotopes
2.1.5Stable & Unstable Nuclei
2.1.6End of Topic Test - Isotopes & Nuclei
2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei
2.1.8Particles, Antiparticles & Photons
2.1.9Particle Interactions
2.1.10Classification of Particles
2.1.11End of Topic Test - Particles & Interactions
2.1.12Quarks & Antiquarks
2.1.13Application of Conservation Laws
2.1.14End of Topic Test - Leptons & Quarks
2.1.15Exam-Style Question - Radioactive Decay
2.2Electromagnetic Radiation & Quantum Phenomena
3Waves
3.1Progressive & Stationary Waves
3.2Refraction, Diffraction & Interference
4Mechanics & Materials
4.1Force, Energy & Momentum
4.1.1Scalars & Vectors
4.1.2Vector Problems
4.1.3End of Topic Test - Scalars & Vectors
4.1.4Moments
4.1.5Centre of Mass
4.1.6End of Topic Test - Moments & Centre of Mass
4.1.7Motion in a Straight Line
4.1.8Graphs of Motion
4.1.9Bouncing Ball Example
4.1.10End of Topic Test - Motion in a Straight Line
4.1.11Acceleration Due to Gravity
4.1.12Projectile Motion
4.1.13Friction
4.1.14Terminal Speed
4.1.15End of Topic Test - Acceleration Due to Gravity
4.1.16Newton's Laws
4.1.17Momentum
4.1.18Momentum 2
4.1.19End of Topic Test - Newton's Laws & Momentum
4.1.20A-A* (AO3/4) - Newton's Third Law
4.1.21Work & Energy
4.1.22Power & Efficiency
4.1.23Conservation of Energy
4.1.24End of Topic Test - Work, Energy & Power
4.1.25Exam-Style Question - Forces
5Electricity
5.1Current Electricity
5.1.1Basics of Electricity
5.1.2Current-Voltage Characteristics
5.1.3End of Topic Test - Basics of Electricity
5.1.4Resistivity
5.1.5Superconductivity
5.1.6A-A* (AO3/4) - Superconductivity
5.1.7End of Topic Test - Resistivity & Superconductors
5.1.8Circuits
5.1.9Power and Conservation
5.1.10Potential Divider
5.1.11Emf & Internal Resistance
5.1.12End of Topic Test - Power & Potential
5.1.13Exam-Style Question - Resistance
6Further Mechanics & Thermal Physics (A2 only)
6.1Periodic Motion (A2 only)
6.2Thermal Physics (A2 only)
7Fields & Their Consequences (A2 only)
7.1Fields (A2 only)
7.2Gravitational Fields (A2 only)
7.3Electric Fields (A2 only)
7.4Capacitance (A2 only)
7.5Magnetic Fields (A2 only)
7.5.1Magnetic Flux Density
7.5.2End of Topic Test - Capacitance & Flux Density
7.5.3Moving Charges in a Magnetic Field
7.5.4Magnetic Flux & Flux Linkage
7.5.5Electromagnetic Induction
7.5.6Electromagnetic Induction 2
7.5.7Alternating Currents
7.5.8Operation of a Transformer
7.5.9Magnetic Flux Density
7.5.10End of Topic Test - Electromagnetic Induction
8Nuclear Physics (A2 only)
8.1Radioactivity (A2 only)
8.1.1Rutherford Scattering
8.1.2Alpha & Beta Radiation
8.1.3Gamma Radiation
8.1.4Radioactive Decay
8.1.5Half Life
8.1.6End of Topic Test - Radioactivity
8.1.7Nuclear Instability
8.1.8Nuclear Radius
8.1.9Mass & Energy
8.1.10Binding Energy
8.1.11Induced Fission
8.1.12Safety Aspects of Nuclear Reactors
8.1.13End of Topic Test - Nuclear Physics
8.1.14A-A* (AO3/4) - Nuclear Fusion
9Option: Astrophysics (A2 only)
9.1Telescopes (A2 only)
9.2Classification of Stars (A2 only)
9.3Cosmology (A2 only)
10Option: Medical Physics (A2 only)
10.1Physics of the Eye (A2 only)
10.2Physics of the Ear (A2 only)
10.3Biological Measurement (A2 only)
10.4Non-Ionising Imaging (A2 only)
10.5X-Ray Imaging (A2 only)
10.6Radionuclide Imaging & Therapy (A2 only)
11Option: Engineering Physics (A2 only)
11.1Rotational Dynamics (A2 only)
11.2Thermodynamics & Engines (A2 only)
12Option: Turning Points in Physics (A2 only)
12.1Discovery of the Electron (A2 only)
12.2Wave-Particle Duality (A2 only)
Jump to other topics
1Measurements & Errors
2Particles & Radiation
2.1Particles
2.1.1Atomic Model
2.1.2Specific Charge, Protons & Neutron Numbers
2.1.3End of Topic Test - Atomic Model
2.1.4Isotopes
2.1.5Stable & Unstable Nuclei
2.1.6End of Topic Test - Isotopes & Nuclei
2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei
2.1.8Particles, Antiparticles & Photons
2.1.9Particle Interactions
2.1.10Classification of Particles
2.1.11End of Topic Test - Particles & Interactions
2.1.12Quarks & Antiquarks
2.1.13Application of Conservation Laws
2.1.14End of Topic Test - Leptons & Quarks
2.1.15Exam-Style Question - Radioactive Decay
2.2Electromagnetic Radiation & Quantum Phenomena
3Waves
3.1Progressive & Stationary Waves
3.2Refraction, Diffraction & Interference
4Mechanics & Materials
4.1Force, Energy & Momentum
4.1.1Scalars & Vectors
4.1.2Vector Problems
4.1.3End of Topic Test - Scalars & Vectors
4.1.4Moments
4.1.5Centre of Mass
4.1.6End of Topic Test - Moments & Centre of Mass
4.1.7Motion in a Straight Line
4.1.8Graphs of Motion
4.1.9Bouncing Ball Example
4.1.10End of Topic Test - Motion in a Straight Line
4.1.11Acceleration Due to Gravity
4.1.12Projectile Motion
4.1.13Friction
4.1.14Terminal Speed
4.1.15End of Topic Test - Acceleration Due to Gravity
4.1.16Newton's Laws
4.1.17Momentum
4.1.18Momentum 2
4.1.19End of Topic Test - Newton's Laws & Momentum
4.1.20A-A* (AO3/4) - Newton's Third Law
4.1.21Work & Energy
4.1.22Power & Efficiency
4.1.23Conservation of Energy
4.1.24End of Topic Test - Work, Energy & Power
4.1.25Exam-Style Question - Forces
5Electricity
5.1Current Electricity
5.1.1Basics of Electricity
5.1.2Current-Voltage Characteristics
5.1.3End of Topic Test - Basics of Electricity
5.1.4Resistivity
5.1.5Superconductivity
5.1.6A-A* (AO3/4) - Superconductivity
5.1.7End of Topic Test - Resistivity & Superconductors
5.1.8Circuits
5.1.9Power and Conservation
5.1.10Potential Divider
5.1.11Emf & Internal Resistance
5.1.12End of Topic Test - Power & Potential
5.1.13Exam-Style Question - Resistance
6Further Mechanics & Thermal Physics (A2 only)
6.1Periodic Motion (A2 only)
6.2Thermal Physics (A2 only)
7Fields & Their Consequences (A2 only)
7.1Fields (A2 only)
7.2Gravitational Fields (A2 only)
7.3Electric Fields (A2 only)
7.4Capacitance (A2 only)
7.5Magnetic Fields (A2 only)
7.5.1Magnetic Flux Density
7.5.2End of Topic Test - Capacitance & Flux Density
7.5.3Moving Charges in a Magnetic Field
7.5.4Magnetic Flux & Flux Linkage
7.5.5Electromagnetic Induction
7.5.6Electromagnetic Induction 2
7.5.7Alternating Currents
7.5.8Operation of a Transformer
7.5.9Magnetic Flux Density
7.5.10End of Topic Test - Electromagnetic Induction
8Nuclear Physics (A2 only)
8.1Radioactivity (A2 only)
8.1.1Rutherford Scattering
8.1.2Alpha & Beta Radiation
8.1.3Gamma Radiation
8.1.4Radioactive Decay
8.1.5Half Life
8.1.6End of Topic Test - Radioactivity
8.1.7Nuclear Instability
8.1.8Nuclear Radius
8.1.9Mass & Energy
8.1.10Binding Energy
8.1.11Induced Fission
8.1.12Safety Aspects of Nuclear Reactors
8.1.13End of Topic Test - Nuclear Physics
8.1.14A-A* (AO3/4) - Nuclear Fusion
9Option: Astrophysics (A2 only)
9.1Telescopes (A2 only)
9.2Classification of Stars (A2 only)
9.3Cosmology (A2 only)
10Option: Medical Physics (A2 only)
10.1Physics of the Eye (A2 only)
10.2Physics of the Ear (A2 only)
10.3Biological Measurement (A2 only)
10.4Non-Ionising Imaging (A2 only)
10.5X-Ray Imaging (A2 only)
10.6Radionuclide Imaging & Therapy (A2 only)
11Option: Engineering Physics (A2 only)
11.1Rotational Dynamics (A2 only)
11.2Thermodynamics & Engines (A2 only)
12Option: Turning Points in Physics (A2 only)
12.1Discovery of the Electron (A2 only)
12.2Wave-Particle Duality (A2 only)
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