2.2.4
Collisions of Electrons with Atoms
Ionisation and Excitation
Ionisation and Excitation
Both electrons being removed from an atom and the movement of electrons within energy levels in the atom explain commonly observed phenomena.
Ionisation
Ionisation
- To ionise an atom means to remove or add electrons to an atom.
- Ionisation in the context of quantum phenomena almost always means the removal of electrons completely from the atom.
- The energy needed for an electron to go from the ground state to being completely removed is called the ionisation energy.
Excitation
Excitation
- Electrons can also be made to move from one energy level to the other.
- To do this, the electron needs exactly the energy difference between energy levels.
- One way to do this is for a photon to interact with the electron.
- The electron will absorb all the energy of the photon.
Excitation 2
Excitation 2
- If the energy of the photon is exactly the energy difference between the energy levels, the electron will move up the energy levels.
- When an electron has moved up energy levels we called the electron "excited".
- The process of making the electron move up energy levels is called "excitation".
Fluorescent Tubes
Fluorescent Tubes
It is important to understand how fluorescent tubes work.
Constituents of the tube
Constituents of the tube
- A fluorescent tube has mercury vapour inside it.
- A fluorescent tube is coated on the inside with phosphor.
- There are free electrons in the fluorescent tube.
- A high voltage will accelerate these free electrons.
Excitation of electrons
Excitation of electrons
- The high-energy free electrons then ionise the mercury vapour.
- This means that there are more free electrons than previously.
- The free electrons then excite electrons in the mercury atoms.
Release of photons
Release of photons
- The excited electrons then move back to their ground state.
- When they do so, they release the excess energy in the form of photons.
- These photons are high-frequency, high-energy, ultraviolet photons.
Absorption of high-energy photons
Absorption of high-energy photons
- The ultra-violet photons then collide with the phosphor coating on the inside of the tube.
- The electrons in the phosphor are now excited.
Release of visible light photons
Release of visible light photons
- The excited electrons then eventually move back to their ground state. When they do so, they release the excess energy in the form of photons.
- These photons have a frequency in the visible range.
The Electron Volt
The Electron Volt
When dealing with energy levels of individual atoms, the SI unit of energy (the Joule, J) is far too big. So we need to define a more appropriate unit of energy, the electron volt, eV.
Definition of electron volt
Definition of electron volt
- The electron volt is defined as the energy given to a fundamental charge, e, accelerated through a potential difference of 1 Volt.
Conversion
Conversion
- To convert between J and eV, simply multiply or divide by the charge of the electron, e = 1.6×10-19.
- 1 eV = 1.6 ×10-19 J
Example - hydrogen
Example - hydrogen
- Let's say the energy of an electron in a hydrogen atom is 13.6 eV.
- To find this in Joules, use the equation shown previously:
- 13.6 eV = 13.6 × 1.6 ×10-19 J
- 13.6 eV = 2.18 ×10-18 J (3 s.f.)
1Measurements & Errors
2Particles & Radiation
2.1Particles
2.1.1Atomic Model
2.1.2Specific Charge, Protons & Neutron Numbers
2.1.3End of Topic Test - Atomic Model
2.1.4Isotopes
2.1.5Stable & Unstable Nuclei
2.1.6End of Topic Test - Isotopes & Nuclei
2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei
2.1.8Particles, Antiparticles & Photons
2.1.9Particle Interactions
2.1.10Classification of Particles
2.1.11End of Topic Test - Particles & Interactions
2.1.12Quarks & Antiquarks
2.1.13Application of Conservation Laws
2.1.14End of Topic Test - Leptons & Quarks
2.1.15Exam-Style Question - Radioactive Decay
2.2Electromagnetic Radiation & Quantum Phenomena
3Waves
3.1Progressive & Stationary Waves
3.2Refraction, Diffraction & Interference
4Mechanics & Materials
4.1Force, Energy & Momentum
4.1.1Scalars & Vectors
4.1.2Vector Problems
4.1.3End of Topic Test - Scalars & Vectors
4.1.4Moments
4.1.5Centre of Mass
4.1.6End of Topic Test - Moments & Centre of Mass
4.1.7Motion in a Straight Line
4.1.8Graphs of Motion
4.1.9Bouncing Ball Example
4.1.10End of Topic Test - Motion in a Straight Line
4.1.11Acceleration Due to Gravity
4.1.12Projectile Motion
4.1.13Friction
4.1.14Terminal Speed
4.1.15End of Topic Test - Acceleration Due to Gravity
4.1.16Newton's Laws
4.1.17Momentum
4.1.18Momentum 2
4.1.19End of Topic Test - Newton's Laws & Momentum
4.1.20A-A* (AO3/4) - Newton's Third Law
4.1.21Work & Energy
4.1.22Power & Efficiency
4.1.23Conservation of Energy
4.1.24End of Topic Test - Work, Energy & Power
4.1.25Exam-Style Question - Forces
5Electricity
5.1Current Electricity
5.1.1Basics of Electricity
5.1.2Current-Voltage Characteristics
5.1.3End of Topic Test - Basics of Electricity
5.1.4Resistivity
5.1.5Superconductivity
5.1.6A-A* (AO3/4) - Superconductivity
5.1.7End of Topic Test - Resistivity & Superconductors
5.1.8Circuits
5.1.9Power and Conservation
5.1.10Potential Divider
5.1.11Emf & Internal Resistance
5.1.12End of Topic Test - Power & Potential
5.1.13Exam-Style Question - Resistance
6Further Mechanics & Thermal Physics (A2 only)
6.1Periodic Motion (A2 only)
6.2Thermal Physics (A2 only)
7Fields & Their Consequences (A2 only)
7.1Fields (A2 only)
7.2Gravitational Fields (A2 only)
7.3Electric Fields (A2 only)
7.4Capacitance (A2 only)
7.5Magnetic Fields (A2 only)
7.5.1Magnetic Flux Density
7.5.2End of Topic Test - Capacitance & Flux Density
7.5.3Moving Charges in a Magnetic Field
7.5.4Magnetic Flux & Flux Linkage
7.5.5Electromagnetic Induction
7.5.6Electromagnetic Induction 2
7.5.7Alternating Currents
7.5.8Operation of a Transformer
7.5.9Magnetic Flux Density
7.5.10End of Topic Test - Electromagnetic Induction
8Nuclear Physics (A2 only)
8.1Radioactivity (A2 only)
8.1.1Rutherford Scattering
8.1.2Alpha & Beta Radiation
8.1.3Gamma Radiation
8.1.4Radioactive Decay
8.1.5Half Life
8.1.6End of Topic Test - Radioactivity
8.1.7Nuclear Instability
8.1.8Nuclear Radius
8.1.9Mass & Energy
8.1.10Binding Energy
8.1.11Induced Fission
8.1.12Safety Aspects of Nuclear Reactors
8.1.13End of Topic Test - Nuclear Physics
8.1.14A-A* (AO3/4) - Nuclear Fusion
9Option: Astrophysics (A2 only)
9.1Telescopes (A2 only)
9.2Classification of Stars (A2 only)
9.3Cosmology (A2 only)
10Option: Medical Physics (A2 only)
10.1Physics of the Eye (A2 only)
10.2Physics of the Ear (A2 only)
10.3Biological Measurement (A2 only)
10.4Non-Ionising Imaging (A2 only)
10.5X-Ray Imaging (A2 only)
10.6Radionuclide Imaging & Therapy (A2 only)
11Option: Engineering Physics (A2 only)
11.1Rotational Dynamics (A2 only)
11.2Thermodynamics & Engines (A2 only)
12Option: Turning Points in Physics (A2 only)
12.1Discovery of the Electron (A2 only)
12.2Wave-Particle Duality (A2 only)
Jump to other topics
1Measurements & Errors
2Particles & Radiation
2.1Particles
2.1.1Atomic Model
2.1.2Specific Charge, Protons & Neutron Numbers
2.1.3End of Topic Test - Atomic Model
2.1.4Isotopes
2.1.5Stable & Unstable Nuclei
2.1.6End of Topic Test - Isotopes & Nuclei
2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei
2.1.8Particles, Antiparticles & Photons
2.1.9Particle Interactions
2.1.10Classification of Particles
2.1.11End of Topic Test - Particles & Interactions
2.1.12Quarks & Antiquarks
2.1.13Application of Conservation Laws
2.1.14End of Topic Test - Leptons & Quarks
2.1.15Exam-Style Question - Radioactive Decay
2.2Electromagnetic Radiation & Quantum Phenomena
3Waves
3.1Progressive & Stationary Waves
3.2Refraction, Diffraction & Interference
4Mechanics & Materials
4.1Force, Energy & Momentum
4.1.1Scalars & Vectors
4.1.2Vector Problems
4.1.3End of Topic Test - Scalars & Vectors
4.1.4Moments
4.1.5Centre of Mass
4.1.6End of Topic Test - Moments & Centre of Mass
4.1.7Motion in a Straight Line
4.1.8Graphs of Motion
4.1.9Bouncing Ball Example
4.1.10End of Topic Test - Motion in a Straight Line
4.1.11Acceleration Due to Gravity
4.1.12Projectile Motion
4.1.13Friction
4.1.14Terminal Speed
4.1.15End of Topic Test - Acceleration Due to Gravity
4.1.16Newton's Laws
4.1.17Momentum
4.1.18Momentum 2
4.1.19End of Topic Test - Newton's Laws & Momentum
4.1.20A-A* (AO3/4) - Newton's Third Law
4.1.21Work & Energy
4.1.22Power & Efficiency
4.1.23Conservation of Energy
4.1.24End of Topic Test - Work, Energy & Power
4.1.25Exam-Style Question - Forces
5Electricity
5.1Current Electricity
5.1.1Basics of Electricity
5.1.2Current-Voltage Characteristics
5.1.3End of Topic Test - Basics of Electricity
5.1.4Resistivity
5.1.5Superconductivity
5.1.6A-A* (AO3/4) - Superconductivity
5.1.7End of Topic Test - Resistivity & Superconductors
5.1.8Circuits
5.1.9Power and Conservation
5.1.10Potential Divider
5.1.11Emf & Internal Resistance
5.1.12End of Topic Test - Power & Potential
5.1.13Exam-Style Question - Resistance
6Further Mechanics & Thermal Physics (A2 only)
6.1Periodic Motion (A2 only)
6.2Thermal Physics (A2 only)
7Fields & Their Consequences (A2 only)
7.1Fields (A2 only)
7.2Gravitational Fields (A2 only)
7.3Electric Fields (A2 only)
7.4Capacitance (A2 only)
7.5Magnetic Fields (A2 only)
7.5.1Magnetic Flux Density
7.5.2End of Topic Test - Capacitance & Flux Density
7.5.3Moving Charges in a Magnetic Field
7.5.4Magnetic Flux & Flux Linkage
7.5.5Electromagnetic Induction
7.5.6Electromagnetic Induction 2
7.5.7Alternating Currents
7.5.8Operation of a Transformer
7.5.9Magnetic Flux Density
7.5.10End of Topic Test - Electromagnetic Induction
8Nuclear Physics (A2 only)
8.1Radioactivity (A2 only)
8.1.1Rutherford Scattering
8.1.2Alpha & Beta Radiation
8.1.3Gamma Radiation
8.1.4Radioactive Decay
8.1.5Half Life
8.1.6End of Topic Test - Radioactivity
8.1.7Nuclear Instability
8.1.8Nuclear Radius
8.1.9Mass & Energy
8.1.10Binding Energy
8.1.11Induced Fission
8.1.12Safety Aspects of Nuclear Reactors
8.1.13End of Topic Test - Nuclear Physics
8.1.14A-A* (AO3/4) - Nuclear Fusion
9Option: Astrophysics (A2 only)
9.1Telescopes (A2 only)
9.2Classification of Stars (A2 only)
9.3Cosmology (A2 only)
10Option: Medical Physics (A2 only)
10.1Physics of the Eye (A2 only)
10.2Physics of the Ear (A2 only)
10.3Biological Measurement (A2 only)
10.4Non-Ionising Imaging (A2 only)
10.5X-Ray Imaging (A2 only)
10.6Radionuclide Imaging & Therapy (A2 only)
11Option: Engineering Physics (A2 only)
11.1Rotational Dynamics (A2 only)
11.2Thermodynamics & Engines (A2 only)
12Option: Turning Points in Physics (A2 only)
12.1Discovery of the Electron (A2 only)
12.2Wave-Particle Duality (A2 only)
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