6.2.5

Boyle's Law & Charles' Law

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Investigation of Boyle's Law

Boyle’s Law describes the relationship between the pressure and volume of a fixed mass of gas at constant temperature.

Manometer method

Manometer method

  • Use a pump to change the air pressure on one side of the manometer.
  • Use a pressure gauge on the pump side to measure air pressure, which is equal to the pressure of the air in the glass tube.
  • You can measure the volume of trapped air.
  • Record the volume for several different pressure values.
Analysis of manometer method

Analysis of manometer method

  • If you plot a graph of volume against pressure, you get a monotonically decreasing curve.
  • Plot a graph of V-1 against P and the best fit straight line goes through the origin.
  • This verifies that V-1 is directly proportional to the pressure, i.e. pV is a constant or that P and V are inversely proportional to each other. This assumes that the temperature and mass of the gas is constant.
Further analysis of manometer method

Further analysis of manometer method

  • You can use a logarithmic plot.
    • Plot log(V) against log (P). It doesn’t matter what base logarithm you use.
    • The gradient of the line of best fit should be -1.
  • Assume V = k/P where k is a constant.
    • log(V) = log(k) - log(P).
    • log(V) = - log(P) + log(k).
Further analysis of manometer method 2

Further analysis of manometer method 2

  • Compare the last line with y = mx + c.
  • If log(V) is plotted on the y-axis, with log(P) on the x-axis, the gradient = -1 and the y-intercept should be log(k).
  • You can find the constant, k, using k = Zc, where Z is the base of the logarithms (i.e. 10 or e) and c is the y-intercept.

Investigation of Boyle's Law 2

Boyle’s Law describes the relationship between the pressure and volume of a fixed mass of gas at constant temperature.

Syringe and data logging method

Syringe and data logging method

  • Connect the open end of a syringe to a pressure sensor (which is then connected to data logger and computer).
  • Start recording on data logger.
  • Move the plunger in steps, i.e. decrease or increase the volume of trapped gas slowly so as not to warm or cool the gas.
  • For each new volume, record the pressure.
Syringe and data logging method 2

Syringe and data logging method 2

  • Use software, such as a spreadsheet, to plot a graph of volume against pressure to get a monotonically decreasing curve.
  • Use software to plot a graph of V-1 against P.
  • The best fit straight line should go through the origin, verifying that V-1 is directly proportional to P.
    • i.e. PV = constant or that P and V are inversely proportional to each other, assuming that the temperature and mass of the gas is constant.

Investigation of Charles’ Law

Charles’ Law describes the relationship between the volume and absolute temperature of a fixed mass of gas at constant pressure.

Apparatus

Apparatus

  • Set up the apparatus as shown in the diagram.
  • Caution: it is common practice to use a kerosene-based oil, which needed a separate risk assessment because it is available via CLEAPPS.
Method

Method

  • Keep stirring the water so as to reduce temperature gradients through the water.
  • The length of the air column is directly proportional to the volume of trapped air. This assumes that the inner diameter of the capillary tube is constant.
Analysis

Analysis

  • Plot a graph of the length of air column against temperature on a graph with axes as shown in the diagram.
    • I.e. extended back to -400 °C so that an extrapolation back to the temperature axis can give a value for absolute zero.
  • Notice that the values of volume and temperature are all bunched to the right.
Analysis 2

Analysis 2

  • The extrapolation is suspect because you have to extrapolate a long way before the line hits the temperature axis.
  • Repeating this with different gases, different volumes of gas and at different pressures gives different straight lines. All of the best fit straight lines should pass through the same point on the temperature axis.
Plot the graph again

Plot the graph again

  • If you plot the graph again using the student’s value for absolute zero, the length-temperature graph becomes a straight line through the origin as shown.
  • This shows that the volume of gas is directly proportional to the temperature in Kelvin. This assumes that the pressure and mass of the gas are constant.
Jump to other topics
1

Measurements & Errors

1.1

Measurements & Errors

1.1.1SI Base Units1.1.2Combining SI Units1.1.3Prefixes of Units1.1.4Standard Form1.1.5Converting Units1.1.6End of Topic Test - Units & Prefixes1.1.7Limitation of Physical Measurements1.1.8Uncertainty1.1.9Estimation1.1.10End of Topic Test - Measurements & Errors1.1.11Diagnostic Misconceptions - Converting between SI1.1.12Diagnostic Misconceptions - SI & Area/Volume
2

Particles & Radiation

2.1

Particles

2.1.1Atomic Model2.1.2Specific Charge, Protons & Neutron Numbers2.1.3End of Topic Test - Atomic Model2.1.4Isotopes2.1.5Stable & Unstable Nuclei2.1.6End of Topic Test - Isotopes & Nuclei2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei2.1.8Particles, Antiparticles & Photons2.1.9Particle Interactions2.1.10Classification of Particles2.1.11End of Topic Test - Particles & Interactions2.1.12Quarks & Antiquarks2.1.13Application of Conservation Laws2.1.14End of Topic Test - Leptons & Quarks2.1.15Exam-Style Question - Radioactive Decay
2.2

Electromagnetic Radiation & Quantum Phenomena

2.2.1The Photoelectric Effect2.2.2The Photoelectric Effect Explanation2.2.3End of Topic Test - The Photoelectric Effect2.2.4Collisions of Electrons with Atoms2.2.5Energy Levels & Photon Emission2.2.6Wave-Particle Duality2.2.7End of Topic Test - Absorption & Emission2.2.8Diagnostic Misconceptions - Electron Volts2.2.9Diagnostic Misconceptions - Converting eV & Joules
3

Waves

3.1

Progressive & Stationary Waves

3.1.1Progressive Waves3.1.2Wave Speed & Phase Difference3.1.3Longitudinal & Transverse Waves3.1.4End of Topic Test - Progressive Waves3.1.5Polarisation3.1.6Stationary Waves3.1.7Stationary Waves 23.1.8End of Topic Test - Polarisation & Stationary Wave3.1.9A-A* (AO3/4) - Stationary Waves
3.2

Refraction, Diffraction & Interference

3.2.1Interference3.2.2Interference 23.2.3End of Topic Test - Interference3.2.4Diffraction3.2.5Diffraction Gratings3.2.6End of Topic Test - Diffraction3.2.7Refraction at a Plane Surface3.2.8Internal Reflection & Fibre Optics3.2.9End of Topic Test - Refraction3.2.10Exam-Style Question - Waves
4

Mechanics & Materials

4.1

Force, Energy & Momentum

4.1.1Scalars & Vectors4.1.2Vector Problems4.1.3End of Topic Test - Scalars & Vectors4.1.4Moments4.1.5Centre of Mass4.1.6End of Topic Test - Moments & Centre of Mass4.1.7Motion in a Straight Line4.1.8Graphs of Motion4.1.9Bouncing Ball Example4.1.10End of Topic Test - Motion in a Straight Line4.1.11Acceleration Due to Gravity4.1.12Projectile Motion4.1.13Friction4.1.14Terminal Speed4.1.15End of Topic Test - Acceleration Due to Gravity4.1.16Newton's Laws4.1.17Momentum4.1.18Momentum 24.1.19End of Topic Test - Newton's Laws & Momentum4.1.20A-A* (AO3/4) - Newton's Third Law4.1.21Work & Energy4.1.22Power & Efficiency4.1.23Conservation of Energy4.1.24End of Topic Test - Work, Energy & Power4.1.25Exam-Style Question - Forces4.1.26Diagnostic Misconceptions - Perpendicular Vectors4.1.27Diagnostic Misconceptions - Weight Acts Downwards4.1.28Diagnostic Misconceptions - Acceleration Direction4.1.29Diagnostic Misconceptions - Stationary Objects4.1.30Diagnostic Misconceptions - Action & Reaction4.1.31Diagnostic Misconceptions - RF Direction4.1.32Diagnostic Misconceptions - RF Acceleration4.1.33Diagnostic Misconceptions - Change in Momentum
4.2

Materials

4.2.1Density4.2.2Bulk Properties of Solids4.2.3Energy in Materials4.2.4Young Modulus4.2.5End of Topic Test - Materials
5

Electricity

5.1

Current Electricity

5.1.1Basics of Electricity5.1.2Current-Voltage Characteristics5.1.3End of Topic Test - Basics of Electricity5.1.4Resistivity5.1.5Superconductivity5.1.6A-A* (AO3/4) - Superconductivity5.1.7End of Topic Test - Resistivity & Superconductors5.1.8Circuits5.1.9Power and Conservation5.1.10Potential Divider5.1.11Emf & Internal Resistance5.1.12End of Topic Test - Power & Potential5.1.13Exam-Style Question - Resistance5.1.14Diagnostic Misconceptions - Constant Current5.1.15Diagnostic Misconceptions - Potential Difference
6

Further Mechanics & Thermal Physics (A2 only)

6.1

Periodic Motion (A2 only)

6.1.1Circular Motion6.1.2Circular Motion 26.1.3End of Topic Test - Circular Motion6.1.4Simple Harmonic Motion6.1.5Simple Harmonic Systems6.1.6Energy in Simple Harmonic Motion6.1.7Resonance6.1.8End of Topic Test - Simple Harmonic Motion6.1.9A-A* (AO3/4) - Simple Harmonic Motion
6.2

Thermal Physics (A2 only)

6.2.1Thermal Energy Transfer6.2.2Thermal Energy Transfer Experiments6.2.3Ideal Gases6.2.4Ideal Gases 26.2.5Boyle's Law & Charles' Law6.2.6Molecular Kinetic Theory Model6.2.7Molecular Kinetic Theory Model 26.2.8End of Topic Test - Thermal Energy & Ideal Gases6.2.9Exam-Style Question - Ideal Gases6.2.10Diagnostic Misconceptions - Material & Mass6.2.11Diagnostic Misconceptions - No Energy
7

Fields & Their Consequences (A2 only)

7.1

Fields (A2 only)

7.1.1Fields
7.2

Gravitational Fields (A2 only)

7.2.1Newton's Law7.2.2Gravitational Field Strength7.2.3Gravitational Potential7.2.4Orbits of Planets & Satellites7.2.5Escape Velocity & Synchronous Orbits7.2.6End of Topic Test - Gravitational Fields
7.3

Electric Fields (A2 only)

7.3.1Coulomb's Law7.3.2Electric Field Strength7.3.3Electric Field Strength 27.3.4Electric Potential7.3.5End of Topic Test - Electric Fields7.3.6A-A* (AO3/4) - Electric and Gravitational Field
7.4

Capacitance (A2 only)

7.4.1Capacitance7.4.2Parallel Plate Capacitor7.4.3Energy Stored by a Capacitor7.4.4Capacitor Discharge7.4.5Capacitor Charge
7.5

Magnetic Fields (A2 only)

7.5.1Magnetic Flux Density7.5.2End of Topic Test - Capacitance & Flux Density7.5.3Moving Charges in a Magnetic Field7.5.4Magnetic Flux & Flux Linkage7.5.5Electromagnetic Induction7.5.6Electromagnetic Induction 27.5.7Alternating Currents7.5.8Operation of a Transformer7.5.9Magnetic Flux Density7.5.10End of Topic Test - Electromagnetic Induction
8

Nuclear Physics (A2 only)

8.1

Radioactivity (A2 only)

8.1.1Rutherford Scattering8.1.2Alpha & Beta Radiation8.1.3Gamma Radiation8.1.4Radioactive Decay8.1.5Half Life8.1.6End of Topic Test - Radioactivity8.1.7Nuclear Instability8.1.8Nuclear Radius8.1.9Mass & Energy8.1.10Binding Energy8.1.11Induced Fission8.1.12Safety Aspects of Nuclear Reactors8.1.13End of Topic Test - Nuclear Physics8.1.14A-A* (AO3/4) - Nuclear Fusion
9

Option: Astrophysics (A2 only)

9.1

Telescopes (A2 only)

9.1.1Astronomical Telescopes9.1.2Reflecting Telescopes9.1.3Single Dish Radio Telescopes9.1.4Large Diameter Telescopes
9.2

Classification of Stars (A2 only)

9.2.1Classification by Luminosity9.2.2Absolute Magnitude9.2.3Black Body Radiation9.2.4Stellar Spectral Classes9.2.5Hertzsprung-Russell Diagrams9.2.6Astronomical Objects
9.3

Cosmology (A2 only)

9.3.1Doppler Effect9.3.2Hubble's Law9.3.3Quasars9.3.4Detecting Exoplanets
10

Option: Medical Physics (A2 only)

10.1

Physics of the Eye (A2 only)

10.1.1Physics of Vision10.1.2Defects of Vision10.1.3Lenses10.1.4Correcting Defects of Vision
10.2

Physics of the Ear (A2 only)

10.2.1Structure of the Ear10.2.2Sensitivity of the Ear10.2.3Hearing Defects
10.3

Biological Measurement (A2 only)

10.3.1Electrocardiography (ECG)
10.4

Non-Ionising Imaging (A2 only)

10.4.1Ultrasound Imaging10.4.2Ultrasound Imaging 210.4.3Fibre Optics & Endoscopy10.4.4Magnetic Resonance Scanning
10.5

X-Ray Imaging (A2 only)

10.5.1Diagnostic X-Rays10.5.2X-Ray Image Processing10.5.3Absorption of X-Rays10.5.4CT Scanners
10.6

Radionuclide Imaging & Therapy (A2 only)

10.6.1Imaging Techniques10.6.2Half Life10.6.3Gamma Camera10.6.4High Energy X-Rays10.6.5Radioactive Implants10.6.6Imaging Comparisons
11

Option: Engineering Physics (A2 only)

11.1

Rotational Dynamics (A2 only)

11.1.1Moment of Inertia11.1.2Rotational Kinetic Energy11.1.3Rotational Motion11.1.4Torque & Angular Acceleration11.1.5Angular Momentum11.1.6Angular Work & Power
11.2

Thermodynamics & Engines (A2 only)

11.2.1First Law of Thermodynamics11.2.2Non-Flow Processes11.2.3p-V Diagrams11.2.4Engine Cycles11.2.5Second Law & Engines11.2.6Reversed Heat Engines
12

Option: Turning Points in Physics (A2 only)

12.1

Discovery of the Electron (A2 only)

12.1.1Cathode Rays12.1.2Thermionic Electron Emission12.1.3Electron Specific Charge12.1.4Millikan's Experiment
12.2

Wave-Particle Duality (A2 only)

12.2.1Newton's & Huygen's Theories of Light12.2.2Electromagnetic Waves12.2.3Photoelectricity12.2.4Wave-Particle Duality12.2.5Electron Microscopes
12.3

Special Relativity (A2 only)

12.3.1Michelson-Morley Experiment12.3.2Einstein's Theory of Special Relativity12.3.3Time Dilation12.3.4Length Contraction12.3.5Mass & Energy

Practice questions on Boyle's Law & Charles' Law

Can you answer these? Test yourself with free interactive practice on Seneca — used by over 10 million students.

  1. 1
    How are the pressure and volume of a gas related? Multiple choice
  2. 2
    Investigation of Boyle's LawPut in order
  3. 3
    What should the gradient of a log(V) against log (P) graph be?Multiple choice
  4. 4
    Why is it advisable to use a data logger?Multiple choice
  5. 5
    Which of these statements are true about investigating Boyle's law?True / false
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Ideal Gases 2

Molecular Kinetic Theory Model