Boyle's Law & Charles' Law

Test yourself

Investigation of Boyle's Law

Boyle’s Law describes the relationship between the pressure and volume of a fixed mass of gas at constant temperature.

Manometer method

Use a pump to change the air pressure on one side of the manometer.
Use a pressure gauge on the pump side to measure air pressure, which is equal to the pressure of the air in the glass tube.
You can measure the volume of trapped air.
Record the volume for several different pressure values.

Analysis of manometer method

If you plot a graph of volume against pressure, you get a monotonically decreasing curve.
Plot a graph of V^-1 against P and the best fit straight line goes through the origin.
This verifies that V^-1 is directly proportional to the pressure, i.e. pV is a constant or that P and V are inversely proportional to each other. This assumes that the temperature and mass of the gas is constant.

Further analysis of manometer method

You can use a logarithmic plot.
- Plot log(V) against log (P). It doesn’t matter what base logarithm you use.
- The gradient of the line of best fit should be -1.
Assume V = k/P where k is a constant.
- log(V) = log(k) - log(P).
- log(V) = - log(P) + log(k).

Further analysis of manometer method 2

Compare the last line with y = mx + c.
If log(V) is plotted on the y-axis, with log(P) on the x-axis, the gradient = -1 and the y-intercept should be log(k).
You can find the constant, k, using k = Z^c, where Z is the base of the logarithms (i.e. 10 or e) and c is the y-intercept.

Investigation of Boyle's Law 2

Boyle’s Law describes the relationship between the pressure and volume of a fixed mass of gas at constant temperature.

Syringe and data logging method

Connect the open end of a syringe to a pressure sensor (which is then connected to data logger and computer).
Start recording on data logger.
Move the plunger in steps, i.e. decrease or increase the volume of trapped gas slowly so as not to warm or cool the gas.
For each new volume, record the pressure.

Syringe and data logging method 2

Use software, such as a spreadsheet, to plot a graph of volume against pressure to get a monotonically decreasing curve.
Use software to plot a graph of V^-1 against P.
The best fit straight line should go through the origin, verifying that V^-1 is directly proportional to P.
- i.e. PV = constant or that P and V are inversely proportional to each other, assuming that the temperature and mass of the gas is constant.

Investigation of Charles’ Law

Charles’ Law describes the relationship between the volume and absolute temperature of a fixed mass of gas at constant pressure.

Apparatus

Set up the apparatus as shown in the diagram.
Caution: it is common practice to use a kerosene-based oil, which needed a separate risk assessment because it is available via CLEAPPS.

Method

Keep stirring the water so as to reduce temperature gradients through the water.
The length of the air column is directly proportional to the volume of trapped air. This assumes that the inner diameter of the capillary tube is constant.

Analysis

Plot a graph of the length of air column against temperature on a graph with axes as shown in the diagram.
- I.e. extended back to -400 °C so that an extrapolation back to the temperature axis can give a value for absolute zero.
Notice that the values of volume and temperature are all bunched to the right.

Analysis 2

The extrapolation is suspect because you have to extrapolate a long way before the line hits the temperature axis.
Repeating this with different gases, different volumes of gas and at different pressures gives different straight lines. All of the best fit straight lines should pass through the same point on the temperature axis.

Plot the graph again

If you plot the graph again using the student’s value for absolute zero, the length-temperature graph becomes a straight line through the origin as shown.
This shows that the volume of gas is directly proportional to the temperature in Kelvin. This assumes that the pressure and mass of the gas are constant.

1Measurements & Errors

1.1Measurements & Errors

1.1.1Use of SI Units

1.1.2SI Prefixes, Standard Form & Converting Units

1.1.3End of Topic Test - Units & Prefixes

1.1.4Limitation of Physical Measurements

1.1.5Uncertainty

1.1.6Estimation

1.1.7End of Topic Test - Measurements & Errors

2Particles & Radiation

2.1Particles

2.1.1Atomic Model

2.1.2Specific Charge, Protons & Neutron Numbers

2.1.3End of Topic Test - Atomic Model

2.1.4Isotopes

2.1.5Stable & Unstable Nuclei

2.1.6End of Topic Test - Isotopes & Nuclei

2.1.7A-A* (AO3/4) - Stable & Unstable Nuclei

2.1.8Particles, Antiparticles & Photons

2.1.9Particle Interactions

2.1.10Classification of Particles

2.1.11End of Topic Test - Particles & Interactions

2.1.12Quarks & Antiquarks

2.1.13Application of Conservation Laws

2.1.14End of Topic Test - Leptons & Quarks

2.1.15Exam-Style Question - Radioactive Decay

2.2Electromagnetic Radiation & Quantum Phenomena

2.2.1The Photoelectric Effect

2.2.2The Photoelectric Effect Explanation

2.2.3End of Topic Test - The Photoelectric Effect

2.2.4Collisions of Electrons with Atoms

2.2.5Energy Levels & Photon Emission

2.2.6Wave-Particle Duality

2.2.7End of Topic Test - Absorption & Emission

3Waves

3.1Progressive & Stationary Waves

3.1.1Progressive Waves

3.1.2Wave Speed & Phase Difference

3.1.3Longitudinal & Transverse Waves

3.1.4End of Topic Test - Progressive Waves

3.1.5Polarisation

3.1.6Stationary Waves

3.1.7Stationary Waves 2

3.1.8End of Topic Test - Polarisation & Stationary Wave

3.1.9A-A* (AO3/4) - Stationary Waves

3.2Refraction, Diffraction & Interference

3.2.1Interference

3.2.2Interference 2

3.2.3End of Topic Test - Interference

3.2.4Diffraction

3.2.5Diffraction Gratings

3.2.6End of Topic Test - Diffraction

3.2.7Refraction at a Plane Surface

3.2.8Internal Reflection & Fibre Optics

3.2.9End of Topic Test - Refraction

3.2.10Exam-Style Question - Waves

4Mechanics & Materials

4.1Force, Energy & Momentum

4.2Materials

4.2.1Density

4.2.2Bulk Properties of Solids

4.2.3Energy in Materials

4.2.4Young Modulus

4.2.5End of Topic Test - Materials

5Electricity

5.1Current Electricity

5.1.1Basics of Electricity

5.1.2Current-Voltage Characteristics

5.1.3End of Topic Test - Basics of Electricity

5.1.4Resistivity

5.1.5Superconductivity

5.1.6A-A* (AO3/4) - Superconductivity

5.1.7End of Topic Test - Resistivity & Superconductors

5.1.8Circuits

5.1.9Power and Conservation

5.1.10Potential Divider

5.1.11Emf & Internal Resistance

5.1.12End of Topic Test - Power & Potential

5.1.13Exam-Style Question - Resistance

6Further Mechanics & Thermal Physics (A2 only)

6.1Periodic Motion (A2 only)

6.1.1Circular Motion

6.1.2Circular Motion 2

6.1.3End of Topic Test - Circular Motion

6.1.4Simple Harmonic Motion

6.1.5Simple Harmonic Systems

6.1.6Energy in Simple Harmonic Motion

6.1.7Resonance

6.1.8End of Topic Test - Simple Harmonic Motion

6.1.9A-A* (AO3/4) - Simple Harmonic Motion

6.2Thermal Physics (A2 only)

6.2.1Thermal Energy Transfer

6.2.2Thermal Energy Transfer Experiments

6.2.3Ideal Gases

6.2.4Ideal Gases 2

6.2.5Boyle's Law & Charles' Law

6.2.6Molecular Kinetic Theory Model

6.2.7Molecular Kinetic Theory Model 2

6.2.8End of Topic Test - Thermal Energy & Ideal Gases

6.2.9Exam-Style Question - Ideal Gases

7Fields & Their Consequences (A2 only)

7.1Fields (A2 only)

7.1.1Fields

7.2Gravitational Fields (A2 only)

7.2.1Newton's Law

7.2.2Gravitational Field Strength

7.2.3Gravitational Potential

7.2.4Orbits of Planets & Satellites

7.2.5Escape Velocity & Synchronous Orbits

7.2.6End of Topic Test - Gravitational Fields

7.3Electric Fields (A2 only)

7.3.1Coulomb's Law

7.3.2Electric Field Strength

7.3.3Electric Field Strength 2

7.3.4Electric Potential

7.3.5End of Topic Test - Electric Fields

7.3.6A-A* (AO3/4) - Electric and Gravitational Field

7.4Capacitance (A2 only)

7.4.1Capacitance

7.4.2Parallel Plate Capacitor

7.4.3Energy Stored by a Capacitor

7.4.4Capacitor Discharge

7.4.5Capacitor Charge

7.5Magnetic Fields (A2 only)

7.5.1Magnetic Flux Density

7.5.2End of Topic Test - Capacitance & Flux Density

7.5.3Moving Charges in a Magnetic Field

7.5.4Magnetic Flux & Flux Linkage

7.5.5Electromagnetic Induction

7.5.6Electromagnetic Induction 2

7.5.7Alternating Currents

7.5.8Operation of a Transformer

7.5.9Magnetic Flux Density

7.5.10End of Topic Test - Electromagnetic Induction

8Nuclear Physics (A2 only)

8.1Radioactivity (A2 only)

8.1.1Rutherford Scattering

8.1.2Alpha & Beta Radiation

8.1.3Gamma Radiation

8.1.4Radioactive Decay

8.1.5Half Life

8.1.6End of Topic Test - Radioactivity

8.1.7Nuclear Instability

8.1.8Nuclear Radius

8.1.9Mass & Energy

8.1.10Binding Energy

8.1.11Induced Fission

8.1.12Safety Aspects of Nuclear Reactors

8.1.13End of Topic Test - Nuclear Physics

8.1.14A-A* (AO3/4) - Nuclear Fusion

9Option: Astrophysics (A2 only)

9.1Telescopes (A2 only)

9.1.1Astronomical Telescopes

9.1.2Reflecting Telescopes

9.1.3Single Dish Radio Telescopes

9.1.4Large Diameter Telescopes

9.2Classification of Stars (A2 only)

9.2.1Classification by Luminosity

9.2.2Absolute Magnitude

9.2.3Black Body Radiation

9.2.4Stellar Spectral Classes

9.2.5Hertzsprung-Russell Diagrams

9.2.6Astronomical Objects

9.3Cosmology (A2 only)

9.3.1Doppler Effect

9.3.2Hubble's Law

9.3.3Quasars

9.3.4Detecting Exoplanets

10Option: Medical Physics (A2 only)

10.1Physics of the Eye (A2 only)

10.1.1Physics of Vision

10.1.2Defects of Vision

10.1.3Lenses

10.1.4Correcting Defects of Vision

10.2Physics of the Ear (A2 only)

10.2.1Structure of the Ear

10.2.2Sensitivity of the Ear

10.2.3Hearing Defects

10.3Biological Measurement (A2 only)

10.3.1Electrocardiography (ECG)

10.4Non-Ionising Imaging (A2 only)

10.4.1Ultrasound Imaging

10.4.2Ultrasound Imaging 2

10.4.3Fibre Optics & Endoscopy

10.4.4Magnetic Resonance Scanning

10.5X-Ray Imaging (A2 only)

10.5.1Diagnostic X-Rays

10.5.2X-Ray Image Processing

10.5.3Absorption of X-Rays

10.5.4CT Scanners

10.6Radionuclide Imaging & Therapy (A2 only)

10.6.1Imaging Techniques

10.6.2Half Life

10.6.3Gamma Camera

10.6.4High Energy X-Rays

10.6.5Radioactive Implants

10.6.6Imaging Comparisons

11Option: Engineering Physics (A2 only)

11.1Rotational Dynamics (A2 only)

11.1.1Moment of Inertia

11.1.2Rotational Kinetic Energy

11.1.3Rotational Motion

11.1.4Torque & Angular Acceleration

11.1.5Angular Momentum

11.1.6Angular Work & Power

11.2Thermodynamics & Engines (A2 only)

11.2.1First Law of Thermodynamics

11.2.2Non-Flow Processes

11.2.3p-V Diagrams

11.2.4Engine Cycles

11.2.5Second Law & Engines

11.2.6Reversed Heat Engines

12Option: Turning Points in Physics (A2 only)

12.1Discovery of the Electron (A2 only)

12.1.1Cathode Rays

12.1.2Thermionic Electron Emission

12.1.3Electron Specific Charge

12.1.4Millikan's Experiment

12.2Wave-Particle Duality (A2 only)

12.2.1Newton's & Huygen's Theories of Light

12.2.2Electromagnetic Waves

12.2.3Photoelectricity

12.2.4Wave-Particle Duality

12.2.5Electron Microscopes

12.3Special Relativity (A2 only)

12.3.1Michelson-Morley Experiment

12.3.2Einstein's Theory of Special Relativity

12.3.3Time Dilation

12.3.4Length Contraction

12.3.5Mass & Energy

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