4.1.1
Period 3 Elements & Oxides (A2 Only)
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Reactions of the Third Period with Water
The Third Period elements show many interesting reactions with water.

Reactions of Na with water
- 2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)
- This reaction is vigorous with cold water.
- The solution you get is highly basic.

Reactions of Mg with water
- Mg(s) + 2H2O(l) → Mg(OH)2(aq) + H2(g)
- This reaction is slow with cold water.

Reactions of Mg with steam
- Similarly, if you react magnesium with steam, you get magnesium oxide.
- Mg(s) + H2O(g) → MgO(s) + H2(g)
- This is a vigorous reaction and makes the Mg burn with a white light.
Reactions of the Third Period with Oxygen
The elements of the third period have distinctive and different reactions with oxygen.

Na, Mg, Al oxides
- The equations are:
- 4Na(s) + O2(g) → 2Na2O(s)
- 2Mg(s) + O2(g) → 2MgO(s)
- 4Al(s) + 3O2(g) → 2Al2O3(s)
- The common feature is that these metals form their normal ions: Na+, Mg2+ and Al3+.
- To work out the equations, you just have to balance the overall charge with oxide ions.

Silicon and phosphorus oxides
- These oxides are covalent materials. The reactions for their formation are:
- Si(s) + O2(g) → SiO2(s)
- P4(s) + 5O2(g) → P4O10(s)
- Both of these get the oxidation state of their group:
- Phosphorus is +5 and in group 5.
- Silicon is +4 and in group 4.

Sulfur
- Sulfur can form multiple oxides. The most common are sulfur dioxide and sulfur trioxide.
- The equation for the formation of sulfur dioxide is:
- S8(s) + 8O2(g) → 8SO2(g)
- Sulfur trioxide is made from sulfur dioxide using a catalyst. The equation is:
- 2SO2(g) + O2(g) 2SO3(g)
1Physical Chemistry
1.1Atomic Structure
1.1.1Fundamental Particles1.1.2Isotopes & Mass Number1.1.3Mass Spectrometry1.1.4Electron Shells, Sub-Shells & Orbitals1.1.5Electron Configuration1.1.6Ionisation Energy1.1.7Factors Affecting Ionisation Energies1.1.8Trends of Ionisation1.1.9Specific Impacts on Ionisation Energies1.1.10End of Topic Test - Atomic Structure1.1.11A-A* (AO3/4) - Atomic Structure
1.2Amount of Substance
1.2.1Relative Masses1.2.2The Mole1.2.3The Ideal Gas Equation1.2.4Empirical & Molecular Formulae1.2.5Balanced Equations1.2.6Percentage Yield1.2.7A-A* (AO3/4) - Percentage Yield1.2.8Atom Economy1.2.9End of Topic Test - Amount of Substance1.2.10A-A* (AO3/4) - Substances & Yield1.2.11Diagnostic Misconceptions - Moles
1.3Bonding
1.3.1Ionic Bonding1.3.2Covalent & Dative Bonding1.3.3Carbon Structures1.3.4Metallic Bonding1.3.5Physical Properties1.3.6Shapes of Molecules1.3.7Polarity1.3.8Intermolecular Forces1.3.9Intermolecular Forces 21.3.10End of Topic Test - Bonding1.3.11Exam-Style Question - Shape of Molecules1.3.12A-A* (AO3/4) - Bonding1.3.13Diagnostic Misconceptions - Ions1.3.14Diagnostic Misconceptions - Ionic & Covalent1.3.15Diagnostic Misconceptions - Phase Change1.3.16Diagnostic Misconceptions - Boiling1.3.17Diagnostic Misconceptions - Polar Bonds
1.4Energetics
1.5Kinetics
1.6Equilibria
2Physical Chemistry 2 (A2 Only)
2.1Thermodynamics (A2 Only)
2.2Rate Equations (A2 Only)
2.3The Equilibrium Constant Kp (A2 Only)
2.4Electrochemical Cells (A2 Only)
2.5Acids & Bases (A2 Only)
2.5.1Brønsted-Lowry Acids & Bases (A2 Only)2.5.2pH (A2 Only)2.5.3The Ionic Product of Water (A2 Only)2.5.4Weak Acids & Bases (A2 Only)2.5.5pH Curves & Titrations (A2 Only)2.5.6pH Curves & Titrations 2 (A2 Only)2.5.7Buffer Solutions (A2 Only)2.5.8End of Topic Test - Acids & Bases2.5.9Exam-Style Question - Weak Acids2.5.10A-A* (AO3/4) - Acids & Bases2.5.11Diagnostic Misconceptions - Ammonia is an Alkali2.5.12Diagnostic Misconceptions - Water's Neutrality2.5.13Diagnostic Misconceptions - Concentrate & Strength
3Inorganic Chemistry
3.1Periodicity & Trends
4Inorganic Chemistry 2 (A2 Only)
4.1Period 3 (A2 Only)
4.2Transition Metals (A2 Only)
4.2.1General Properties (A2 Only)4.2.2Substitution Reactions (A2 Only)4.2.3Shapes of Complex Ions (A2 Only)4.2.4Colours of Ions (A2 Only)4.2.5Variable Oxidation States (A2 Only)4.2.6Titrations (A2 Only)4.2.7Homogeneous Catalysts (A2 Only)4.2.8Heterogeneous Catalysts (A2 Only)4.2.9End of Topic Test - Transition Metals4.2.10A-A* (AO3/4) - Transition Metals
4.3Reactions of Ions in Aqueous Solutions (A2 Only)
5Organic Chemistry 1
5.1Introduction
5.2Alkanes
5.3Halogenoalkanes
5.4Alkenes
5.5Alcohols
5.6Organic Analysis
5.7A-A* (AO3/4) - Organic 1
6Organic Chemistry 2 (A2 Only)
6.1Optical Isomerism (A2 Only)
6.2Aldehydes & Ketones (A2 Only)
6.3Carboxylic Acids & Esters (A2 Only)
6.4Aromatic Chemistry (A2 Only)
6.5Amines (A2 Only)
6.6Polymers (A2 Only)
6.7Biological Organic (A2 Only)
6.8Organic Synthesis (A2 Only)
6.9NMR Spectroscopy (A2 Only)
6.10Chromatography (A2 Only)
6.11A-A* (AO3/4) - Organic 2
Jump to other topics
1Physical Chemistry
1.1Atomic Structure
1.1.1Fundamental Particles1.1.2Isotopes & Mass Number1.1.3Mass Spectrometry1.1.4Electron Shells, Sub-Shells & Orbitals1.1.5Electron Configuration1.1.6Ionisation Energy1.1.7Factors Affecting Ionisation Energies1.1.8Trends of Ionisation1.1.9Specific Impacts on Ionisation Energies1.1.10End of Topic Test - Atomic Structure1.1.11A-A* (AO3/4) - Atomic Structure
1.2Amount of Substance
1.2.1Relative Masses1.2.2The Mole1.2.3The Ideal Gas Equation1.2.4Empirical & Molecular Formulae1.2.5Balanced Equations1.2.6Percentage Yield1.2.7A-A* (AO3/4) - Percentage Yield1.2.8Atom Economy1.2.9End of Topic Test - Amount of Substance1.2.10A-A* (AO3/4) - Substances & Yield1.2.11Diagnostic Misconceptions - Moles
1.3Bonding
1.3.1Ionic Bonding1.3.2Covalent & Dative Bonding1.3.3Carbon Structures1.3.4Metallic Bonding1.3.5Physical Properties1.3.6Shapes of Molecules1.3.7Polarity1.3.8Intermolecular Forces1.3.9Intermolecular Forces 21.3.10End of Topic Test - Bonding1.3.11Exam-Style Question - Shape of Molecules1.3.12A-A* (AO3/4) - Bonding1.3.13Diagnostic Misconceptions - Ions1.3.14Diagnostic Misconceptions - Ionic & Covalent1.3.15Diagnostic Misconceptions - Phase Change1.3.16Diagnostic Misconceptions - Boiling1.3.17Diagnostic Misconceptions - Polar Bonds
1.4Energetics
1.5Kinetics
1.6Equilibria
2Physical Chemistry 2 (A2 Only)
2.1Thermodynamics (A2 Only)
2.2Rate Equations (A2 Only)
2.3The Equilibrium Constant Kp (A2 Only)
2.4Electrochemical Cells (A2 Only)
2.5Acids & Bases (A2 Only)
2.5.1Brønsted-Lowry Acids & Bases (A2 Only)2.5.2pH (A2 Only)2.5.3The Ionic Product of Water (A2 Only)2.5.4Weak Acids & Bases (A2 Only)2.5.5pH Curves & Titrations (A2 Only)2.5.6pH Curves & Titrations 2 (A2 Only)2.5.7Buffer Solutions (A2 Only)2.5.8End of Topic Test - Acids & Bases2.5.9Exam-Style Question - Weak Acids2.5.10A-A* (AO3/4) - Acids & Bases2.5.11Diagnostic Misconceptions - Ammonia is an Alkali2.5.12Diagnostic Misconceptions - Water's Neutrality2.5.13Diagnostic Misconceptions - Concentrate & Strength
3Inorganic Chemistry
3.1Periodicity & Trends
4Inorganic Chemistry 2 (A2 Only)
4.1Period 3 (A2 Only)
4.2Transition Metals (A2 Only)
4.2.1General Properties (A2 Only)4.2.2Substitution Reactions (A2 Only)4.2.3Shapes of Complex Ions (A2 Only)4.2.4Colours of Ions (A2 Only)4.2.5Variable Oxidation States (A2 Only)4.2.6Titrations (A2 Only)4.2.7Homogeneous Catalysts (A2 Only)4.2.8Heterogeneous Catalysts (A2 Only)4.2.9End of Topic Test - Transition Metals4.2.10A-A* (AO3/4) - Transition Metals
4.3Reactions of Ions in Aqueous Solutions (A2 Only)
5Organic Chemistry 1
5.1Introduction
5.2Alkanes
5.3Halogenoalkanes
5.4Alkenes
5.5Alcohols
5.6Organic Analysis
5.7A-A* (AO3/4) - Organic 1
6Organic Chemistry 2 (A2 Only)
6.1Optical Isomerism (A2 Only)
6.2Aldehydes & Ketones (A2 Only)
6.3Carboxylic Acids & Esters (A2 Only)
6.4Aromatic Chemistry (A2 Only)
6.5Amines (A2 Only)
6.6Polymers (A2 Only)
6.7Biological Organic (A2 Only)
6.8Organic Synthesis (A2 Only)
6.9NMR Spectroscopy (A2 Only)
6.10Chromatography (A2 Only)
6.11A-A* (AO3/4) - Organic 2
Practice questions on Period 3 Elements & Oxides (A2 Only)
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