1.3.2

Covalent & Dative Bonding

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Covalent Bonding

Covalent bonding happens between non-metals.

Covalent bonds

Covalent bonds

  • A covalent bond is one that contains a shared pair of electrons.
    • Usually, each atom gives one electron to the bond.
  • Molecules have covalent bonds holding the atoms together.
    • Covalent bonds are strong because the shared electrons are attracted to the nucleus of both atoms.
Multiple bonding

Multiple bonding

  • Atoms can also form double (e.g. O2) or triple (e.g. N2) covalent bonds.
    • There are rare examples of quadruple, quintuple, and even sextuple bonds between some heavy metal compounds.
  • Multiple bonds contain shared pairs of electrons just like single bonds.
  • Multiple bonds are usually stronger than single bonds.

Dative Bonding

A dative bond is a special kind of covalent bond.

Dative bonds

Dative bonds

  • A dative bond is a covalent bond in which both electrons in the bond come from one atom.
    • Dative bonds are sometimes called coordinate bonds.
E.g. Ammonium ion

E.g. Ammonium ion

  • Ammonium ions are made of an ammonia molecule that has attached to a hydrogen ion with its lone pair.
  • Both electrons for the coordinate bond come from the nitrogen atom.
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1

Physical Chemistry

1.1

Atomic Structure

1.2

Amount of Substance

1.3

Bonding

1.4

Energetics

1.5

Kinetics

1.6

Equilibria

1.7

Redox

2

Physical Chemistry 2 (A2 Only)

3

Inorganic Chemistry

4

Inorganic Chemistry 2 (A2 Only)

5

Organic Chemistry 1

6

Organic Chemistry 2 (A2 Only)

6.1

Optical Isomerism (A2 Only)

6.2

Aldehydes & Ketones (A2 Only)

6.3

Carboxylic Acids & Esters (A2 Only)

6.4

Aromatic Chemistry (A2 Only)

6.5

Amines (A2 Only)

6.6

Polymers (A2 Only)

6.7

Biological Organic (A2 Only)

6.8

Organic Synthesis (A2 Only)

6.9

NMR Spectroscopy (A2 Only)

6.10

Chromatography (A2 Only)

6.11

A-A* (AO3/4) - Organic 2

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