4.9.7

Heat Engines, Heat Pumps & Refrigerators

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Second Law and Engines

It is impossible for engines to work only using the first law of thermodynamics. The second law must also be obeyed.

Source and sink

Source and sink

  • In order to obey the second law of thermodynamics, all engines need a source and a sink of heat.
  • Because the sink cannot be at absolute zero, no engine can be 100% efficient.
Efficiency

Efficiency

  • Efficiency =WQH=QHQCQH= \frac{W}{Q_H} = \frac{Q_H - Q_C}{Q_H}
Maximising efficiency

Maximising efficiency

  • Maximum efficiency =THTCTH= \frac{T_H - T_C}{T_H}
  • To maximise efficiency, (TH - TC) must be large, but TC is usually limited by the temperature of the environment.
    • TH is limited by the material characteristics of the engine.
  • In modern systems, the use of QH and W is maximised, whilst practical uses for QC are sought.

Reversed heat engines

Any engine that runs from cold to hot is a reversed heat engine.

Fridges

Fridges

  • A reverse heat engine does work to move heat energy from a hot body to a cold body.
  • It is the same as a normal heat engine but the heat energy transferred does not do work, it needs work.
Coefficient of performance

Coefficient of performance

  • The coefficient of performance of a refrigerator is like its efficiency.
    • COP=QcWCOP= \frac{{Q_c}}{W}
  • Where QcQ_c is the heat from the cold reservoir.
Heat pumps

Heat pumps

  • Heat pumps are another type of reversed heat engine.
  • A reverse heat engine does work to move heat energy from a cold body to a hot body.
Coefficient of performance

Coefficient of performance

  • The coefficient of performance of a heat pump is like its efficiency.
    • COP=QhWCOP= \frac{{Q_h}}{W}
  • Where QhQ_h is the heat from the warm reservoir.
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Principles of Science I

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Structure & Bonding

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Properties of Substances

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Cell Structure & Function

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Working with Waves

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Practical Scientific Procedures and Techniques

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Science Investigation Skills

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Principles of Science II

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Extracting Elements

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Organic Chemistry

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Energy Changes in Industry

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The Circulatory System

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Urinary System

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Cell Transport

4.9

Thermal Physics

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Materials

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Fluids

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Contemporary Issues in Science

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