4.9.7
Heat Engines, Heat Pumps & Refrigerators
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Second Law and Engines
It is impossible for engines to work only using the first law of thermodynamics. The second law must also be obeyed.

Source and sink
- In order to obey the second law of thermodynamics, all engines need a source and a sink of heat.
- Because the sink cannot be at absolute zero, no engine can be 100% efficient.

Efficiency
- Efficiency

Maximising efficiency
- Maximum efficiency
- To maximise efficiency, (TH - TC) must be large, but TC is usually limited by the temperature of the environment.
- TH is limited by the material characteristics of the engine.
- In modern systems, the use of QH and W is maximised, whilst practical uses for QC are sought.
Reversed heat engines
Any engine that runs from cold to hot is a reversed heat engine.

Fridges
- A reverse heat engine does work to move heat energy from a hot body to a cold body.
- It is the same as a normal heat engine but the heat energy transferred does not do work, it needs work.

Coefficient of performance
- The coefficient of performance of a refrigerator is like its efficiency.
- Where is the heat from the cold reservoir.

Heat pumps
- Heat pumps are another type of reversed heat engine.
- A reverse heat engine does work to move heat energy from a cold body to a hot body.

Coefficient of performance
- The coefficient of performance of a heat pump is like its efficiency.
- Where is the heat from the warm reservoir.
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model1.1.2Electron Shells, Sub-Shells & Orbitals1.1.3Ionic Bonding1.1.4Representing Ionic Bonds1.1.5Covalent Bonding1.1.6Representing Covalent Bonds1.1.7Metallic Bonding1.1.8Intermolecular Forces1.1.9Intermolecular Forces 21.1.10End of Topic Test - Bonding1.1.11Relative Masses1.1.12The Mole1.1.13Molar Calculations1.1.14Molar Calculations 21.1.15Empirical & Molecular Formulae1.1.16Balanced Equations1.1.17Percentage Yield1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table1.2.2Ionisation Energy1.2.3Factors Affecting Ionisation Energies1.2.4Trends of Ionisation1.2.5Trends in the Periodic Table1.2.6Polarity1.2.7Metals & Non-Metals1.2.8Alkali Metals1.2.9Alkaline Earth Metals1.2.10Reactivity of Alkaline Earth Metals1.2.11Redox1.2.12Transition Metals1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange1.5.2Blood Vessels1.5.3Atherosclerosis1.5.4Skeletal Muscle1.5.5Slow & Fast Twitch Fibres1.5.6Neurones1.5.7Speed of Transmission1.5.8Action Potentials1.5.9End of Topic Test - Neurones & Action Potentials1.5.10Synapses1.5.11Types of Synapse1.5.12Medical Application1.5.13End of Topic Test - Synapses1.5.14Chemical Brain Imbalances1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System4.5.2Blood Vessels4.5.3Blood Transfusion & the ABO Rhesus System4.5.4The Heart4.5.5The Cardiac Cycle4.5.6Cardiac Output4.5.7Coordination of Heart Action4.5.8Heart Dissection4.5.9Controlling Heart Rate4.5.10Electrocardiograms4.5.11Cardiovascular Disease4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency4.9.2Work & Energy4.9.3Conservation of Energy4.9.4Pressure4.9.5First Law of Thermodynamics4.9.6Second Law of Thermodynamics4.9.7Heat Engines, Heat Pumps & Refrigerators4.9.8Non-Flow Processes4.9.9p-V Diagrams4.9.10Ideal Gases4.9.11Ideal Gases 24.9.12Thermal Energy Transfer4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
Jump to other topics
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model1.1.2Electron Shells, Sub-Shells & Orbitals1.1.3Ionic Bonding1.1.4Representing Ionic Bonds1.1.5Covalent Bonding1.1.6Representing Covalent Bonds1.1.7Metallic Bonding1.1.8Intermolecular Forces1.1.9Intermolecular Forces 21.1.10End of Topic Test - Bonding1.1.11Relative Masses1.1.12The Mole1.1.13Molar Calculations1.1.14Molar Calculations 21.1.15Empirical & Molecular Formulae1.1.16Balanced Equations1.1.17Percentage Yield1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table1.2.2Ionisation Energy1.2.3Factors Affecting Ionisation Energies1.2.4Trends of Ionisation1.2.5Trends in the Periodic Table1.2.6Polarity1.2.7Metals & Non-Metals1.2.8Alkali Metals1.2.9Alkaline Earth Metals1.2.10Reactivity of Alkaline Earth Metals1.2.11Redox1.2.12Transition Metals1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange1.5.2Blood Vessels1.5.3Atherosclerosis1.5.4Skeletal Muscle1.5.5Slow & Fast Twitch Fibres1.5.6Neurones1.5.7Speed of Transmission1.5.8Action Potentials1.5.9End of Topic Test - Neurones & Action Potentials1.5.10Synapses1.5.11Types of Synapse1.5.12Medical Application1.5.13End of Topic Test - Synapses1.5.14Chemical Brain Imbalances1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System4.5.2Blood Vessels4.5.3Blood Transfusion & the ABO Rhesus System4.5.4The Heart4.5.5The Cardiac Cycle4.5.6Cardiac Output4.5.7Coordination of Heart Action4.5.8Heart Dissection4.5.9Controlling Heart Rate4.5.10Electrocardiograms4.5.11Cardiovascular Disease4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency4.9.2Work & Energy4.9.3Conservation of Energy4.9.4Pressure4.9.5First Law of Thermodynamics4.9.6Second Law of Thermodynamics4.9.7Heat Engines, Heat Pumps & Refrigerators4.9.8Non-Flow Processes4.9.9p-V Diagrams4.9.10Ideal Gases4.9.11Ideal Gases 24.9.12Thermal Energy Transfer4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
Practice questions on Heat Engines, Heat Pumps & Refrigerators
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- 1The maximum efficiency can be achieved for the:Multiple choice
- 2Which of these is an example of a reversed heat engine?Multiple choice
- 3
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