1.1.9
Intermolecular Forces 2
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Permanent Dipole-Dipole Interactions
Permanent dipole-dipole interactions exist between two permanently polar molecules.
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Permanent dipoles
- Permanent dipoles have a δ- on one side and a δ+ on the other.
- The δ+ of one molecule will attract the δ- of another molecule.
- This means that the molecules will line up throughout a liquid or solid in this fashion.
- Permanent dipole-dipole forces are the second strongest molecular interaction.
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Polar molecules
- Permanent dipole-dipole interactions are only possible in molecules that contain a permanent dipole.
- So they are only found between polar molecules.
Hydrogen Bonds
Hydrogen bonds only exist between some specific types of molecules. These intermolecular forces are stronger than induced and permanent dipole-dipole interactions.

Hydrogen bonds
- A hydrogen bond is the name given to a very strong permanent dipole-permanent dipole force.
- With some elements, hydrogen can form extremely strong dipole-dipole interactions.
- When these are strong enough to be considered a bond, it is called a hydrogen bond.

Where are hydrogen bonds found?
- Hydrogen bonds are found when you have a hydrogen atom bonded to either oxygen, nitrogen, or fluorine.
- That hydrogen atom will form a strong permanent dipole-dipole interaction with another oxygen, nitrogen, or fluorine atom.
- Examples of liquids with hydrogen bonds are:
- Water.
- Hydrogen fluoride.
- Ammonia.

Why do hydrogen bonds form?
- When hydrogen is bonded to an extremely electronegative element, it develops a strong δ+ charge.
- Hydrogen is a very small atom, so it has a high charge density in this situation.
- This allows it to form a strong bond with any highly δ- charged atom.
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model1.1.2Electron Shells, Sub-Shells & Orbitals1.1.3Ionic Bonding1.1.4Representing Ionic Bonds1.1.5Covalent Bonding1.1.6Representing Covalent Bonds1.1.7Metallic Bonding1.1.8Intermolecular Forces1.1.9Intermolecular Forces 21.1.10End of Topic Test - Bonding1.1.11Relative Masses1.1.12The Mole1.1.13Molar Calculations1.1.14Molar Calculations 21.1.15Empirical & Molecular Formulae1.1.16Balanced Equations1.1.17Percentage Yield1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table1.2.2Ionisation Energy1.2.3Factors Affecting Ionisation Energies1.2.4Trends of Ionisation1.2.5Trends in the Periodic Table1.2.6Polarity1.2.7Metals & Non-Metals1.2.8Alkali Metals1.2.9Alkaline Earth Metals1.2.10Reactivity of Alkaline Earth Metals1.2.11Redox1.2.12Transition Metals1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange1.5.2Blood Vessels1.5.3Atherosclerosis1.5.4Skeletal Muscle1.5.5Slow & Fast Twitch Fibres1.5.6Neurones1.5.7Speed of Transmission1.5.8Action Potentials1.5.9End of Topic Test - Neurones & Action Potentials1.5.10Synapses1.5.11Types of Synapse1.5.12Medical Application1.5.13End of Topic Test - Synapses1.5.14Chemical Brain Imbalances1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System4.5.2Blood Vessels4.5.3Blood Transfusion & the ABO Rhesus System4.5.4The Heart4.5.5The Cardiac Cycle4.5.6Cardiac Output4.5.7Coordination of Heart Action4.5.8Heart Dissection4.5.9Controlling Heart Rate4.5.10Electrocardiograms4.5.11Cardiovascular Disease4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency4.9.2Work & Energy4.9.3Conservation of Energy4.9.4Pressure4.9.5First Law of Thermodynamics4.9.6Second Law of Thermodynamics4.9.7Heat Engines, Heat Pumps & Refrigerators4.9.8Non-Flow Processes4.9.9p-V Diagrams4.9.10Ideal Gases4.9.11Ideal Gases 24.9.12Thermal Energy Transfer4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
Jump to other topics
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model1.1.2Electron Shells, Sub-Shells & Orbitals1.1.3Ionic Bonding1.1.4Representing Ionic Bonds1.1.5Covalent Bonding1.1.6Representing Covalent Bonds1.1.7Metallic Bonding1.1.8Intermolecular Forces1.1.9Intermolecular Forces 21.1.10End of Topic Test - Bonding1.1.11Relative Masses1.1.12The Mole1.1.13Molar Calculations1.1.14Molar Calculations 21.1.15Empirical & Molecular Formulae1.1.16Balanced Equations1.1.17Percentage Yield1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table1.2.2Ionisation Energy1.2.3Factors Affecting Ionisation Energies1.2.4Trends of Ionisation1.2.5Trends in the Periodic Table1.2.6Polarity1.2.7Metals & Non-Metals1.2.8Alkali Metals1.2.9Alkaline Earth Metals1.2.10Reactivity of Alkaline Earth Metals1.2.11Redox1.2.12Transition Metals1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange1.5.2Blood Vessels1.5.3Atherosclerosis1.5.4Skeletal Muscle1.5.5Slow & Fast Twitch Fibres1.5.6Neurones1.5.7Speed of Transmission1.5.8Action Potentials1.5.9End of Topic Test - Neurones & Action Potentials1.5.10Synapses1.5.11Types of Synapse1.5.12Medical Application1.5.13End of Topic Test - Synapses1.5.14Chemical Brain Imbalances1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System4.5.2Blood Vessels4.5.3Blood Transfusion & the ABO Rhesus System4.5.4The Heart4.5.5The Cardiac Cycle4.5.6Cardiac Output4.5.7Coordination of Heart Action4.5.8Heart Dissection4.5.9Controlling Heart Rate4.5.10Electrocardiograms4.5.11Cardiovascular Disease4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency4.9.2Work & Energy4.9.3Conservation of Energy4.9.4Pressure4.9.5First Law of Thermodynamics4.9.6Second Law of Thermodynamics4.9.7Heat Engines, Heat Pumps & Refrigerators4.9.8Non-Flow Processes4.9.9p-V Diagrams4.9.10Ideal Gases4.9.11Ideal Gases 24.9.12Thermal Energy Transfer4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
Practice questions on Intermolecular Forces 2
Can you answer these? Test yourself with free interactive practice on Seneca — used by over 10 million students.
- 1A permanent dipole is labelled by which of the following?Multiple choice
- 2A hydrogen bond is a very strong type of what?Multiple choice
- 3
- 4Which of the following could form hydrogen bonds?Multiple choice
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