1.1.14

Molar Calculations 2

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Molar Calculations of Gases

We can also calculate the number of moles of a gas. It is difficult to measure the mass or the concentration of a gas so we must use another equation.

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Avogadro's Law

  • The equation is based upon Avogadro's Law:
    • Avogadro's Law says that at the same temperature and pressure, one mole of two different gases will be the same volume.
  • So, regardless of what the gas is, one mole of a gas will always be a particular volume at a specific temperature and pressure.
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Room temperature and pressure

  • At room temperature and pressure, 24 dm3 is the volume taken up by one mole of any gas.
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The equation for moles in a gas

  • This leads to the equation:
    • Number of moles of a gas = volume of the gas ÷ 24
  • This equation is only true if:
    • The volume is measured in dm3.
    • The gas is at room temperature and pressure.
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The equation for volume of a gas

  • Another form of this equation gives the equation
    • Volume of a gas = moles of the gas × 24
  • This equation volume calculated:
    • Is in dm3.
    • Is correct at room temperature and pressure.
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Converting the equation

  • A useful conversion for this equation is:
    • 1 m3 = 1,000 dm3
  • Alternatively, we can use the converted equation:
    • Number of moles of a gas = volume of the gas ÷ 24,000
    • Volume of a gas = number of moles of the gas × 24,000
    • This is true for the volume in cm3.

Stoichiometry

The stoichiometry of a chemical equation refers to the big numbers that sit before each component in the equation.

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An example

  • In the chemical equation:
    • N2 + 3H2 → 2NH3
  • The stoichiometry refers to the coefficients 1, 3 and 2 that sit before each of the species.
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The coefficients

  • We have seen these coefficients many times before.
    • They balance the equations.
  • The coefficients, however, offer more than balancing equations. They are very useful in molar calculations.
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Use in molar calculations

  • The coefficients are useful as they represent the ratio of the amount of each substance used or gained in the reaction.
    • We know that the number of moles is a measure of the amount of each substance.
    • If we know the number of moles of one species, we can use the coefficients to determine the number of moles of the other species.
    • It is easiest to consider this using an example.
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A calculation example

  • In the reaction:
    • N2 + 3H2 → 2NH3
  • We know there are 0.5 moles of N2
    • Using coefficient ratios, we know there is three times as many moles of H2
    • There are two times as many moles of NH3
  • So:
    • There are 1.5 moles of H2
    • There is 1 mole NH3

Jump to other topics

1Principles of Science I

1.1Structure & Bonding

1.2Properties of Substances

1.3Cell Structure & Function

1.4Cell Specialisation

1.5Tissue Structure & Function

1.6Working with Waves

1.7Waves in Communication

2Practical Scientific Procedures and Techniques

3Science Investigation Skills

4Principles of Science II

4.1Extracting Elements

4.2Relating Properties to use of Substances

4.3Organic Chemistry

4.4Energy Changes in Industry

4.5The Circulatory System

4.6Ventilation & Gas Exchange

4.7Urinary System

4.8Cell Transport

4.9Thermal Physics

4.10Materials

4.11Fluids

5Contemporary Issues in Science

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