1.1.14
Molar Calculations 2
Molar Calculations of Gases
Molar Calculations of Gases
We can also calculate the number of moles of a gas. It is difficult to measure the mass or the concentration of a gas so we must use another equation.


Avogadro's Law
Avogadro's Law
- The equation is based upon Avogadro's Law:
- Avogadro's Law says that at the same temperature and pressure, one mole of two different gases will be the same volume.
- So, regardless of what the gas is, one mole of a gas will always be a particular volume at a specific temperature and pressure.


Room temperature and pressure
Room temperature and pressure
- At room temperature and pressure, 24 dm3 is the volume taken up by one mole of any gas.


The equation for moles in a gas
The equation for moles in a gas
- This leads to the equation:
- Number of moles of a gas = volume of the gas ÷ 24
- This equation is only true if:
- The volume is measured in dm3.
- The gas is at room temperature and pressure.


The equation for volume of a gas
The equation for volume of a gas
- Another form of this equation gives the equation
- Volume of a gas = moles of the gas × 24
- This equation volume calculated:
- Is in dm3.
- Is correct at room temperature and pressure.


Converting the equation
Converting the equation
- A useful conversion for this equation is:
- 1 m3 = 1,000 dm3
- Alternatively, we can use the converted equation:
- Number of moles of a gas = volume of the gas ÷ 24,000
- Volume of a gas = number of moles of the gas × 24,000
- This is true for the volume in cm3.
Stoichiometry
Stoichiometry
The stoichiometry of a chemical equation refers to the big numbers that sit before each component in the equation.


An example
An example
- In the chemical equation:
- N2 + 3H2 → 2NH3
- The stoichiometry refers to the coefficients 1, 3 and 2 that sit before each of the species.


The coefficients
The coefficients
- We have seen these coefficients many times before.
- They balance the equations.
- The coefficients, however, offer more than balancing equations. They are very useful in molar calculations.


Use in molar calculations
Use in molar calculations
- The coefficients are useful as they represent the ratio of the amount of each substance used or gained in the reaction.
- We know that the number of moles is a measure of the amount of each substance.
- If we know the number of moles of one species, we can use the coefficients to determine the number of moles of the other species.
- It is easiest to consider this using an example.


A calculation example
A calculation example
- In the reaction:
- N2 + 3H2 → 2NH3
- We know there are 0.5 moles of N2
- Using coefficient ratios, we know there is three times as many moles of H2
- There are two times as many moles of NH3
- So:
- There are 1.5 moles of H2
- There is 1 mole NH3
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model
1.1.2Electron Shells, Sub-Shells & Orbitals
1.1.3Ionic Bonding
1.1.4Representing Ionic Bonds
1.1.5Covalent Bonding
1.1.6Representing Covalent Bonds
1.1.7Metallic Bonding
1.1.8Intermolecular Forces
1.1.9Intermolecular Forces 2
1.1.10End of Topic Test - Bonding
1.1.11Relative Masses
1.1.12The Mole
1.1.13Molar Calculations
1.1.14Molar Calculations 2
1.1.15Empirical & Molecular Formulae
1.1.16Balanced Equations
1.1.17Percentage Yield
1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table
1.2.2Ionisation Energy
1.2.3Factors Affecting Ionisation Energies
1.2.4Trends of Ionisation
1.2.5Trends in the Periodic Table
1.2.6Polarity
1.2.7Metals & Non-Metals
1.2.8Alkali Metals
1.2.9Alkaline Earth Metals
1.2.10Reactivity of Alkaline Earth Metals
1.2.11Redox
1.2.12Transition Metals
1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange
1.5.2Blood Vessels
1.5.3Atherosclerosis
1.5.4Skeletal Muscle
1.5.5Slow & Fast Twitch Fibres
1.5.6Neurones
1.5.7Speed of Transmission
1.5.8Action Potentials
1.5.9End of Topic Test - Neurones & Action Potentials
1.5.10Synapses
1.5.11Types of Synapse
1.5.12Medical Application
1.5.13End of Topic Test - Synapses
1.5.14Chemical Brain Imbalances
1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System
4.5.2Blood Vessels
4.5.3Blood Transfusion & the ABO Rhesus System
4.5.4The Heart
4.5.5The Cardiac Cycle
4.5.6Cardiac Output
4.5.7Coordination of Heart Action
4.5.8Heart Dissection
4.5.9Controlling Heart Rate
4.5.10Electrocardiograms
4.5.11Cardiovascular Disease
4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency
4.9.2Work & Energy
4.9.3Conservation of Energy
4.9.4Pressure
4.9.5First Law of Thermodynamics
4.9.6Second Law of Thermodynamics
4.9.7Heat Engines, Heat Pumps & Refrigerators
4.9.8Non-Flow Processes
4.9.9p-V Diagrams
4.9.10Ideal Gases
4.9.11Ideal Gases 2
4.9.12Thermal Energy Transfer
4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
Jump to other topics
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model
1.1.2Electron Shells, Sub-Shells & Orbitals
1.1.3Ionic Bonding
1.1.4Representing Ionic Bonds
1.1.5Covalent Bonding
1.1.6Representing Covalent Bonds
1.1.7Metallic Bonding
1.1.8Intermolecular Forces
1.1.9Intermolecular Forces 2
1.1.10End of Topic Test - Bonding
1.1.11Relative Masses
1.1.12The Mole
1.1.13Molar Calculations
1.1.14Molar Calculations 2
1.1.15Empirical & Molecular Formulae
1.1.16Balanced Equations
1.1.17Percentage Yield
1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table
1.2.2Ionisation Energy
1.2.3Factors Affecting Ionisation Energies
1.2.4Trends of Ionisation
1.2.5Trends in the Periodic Table
1.2.6Polarity
1.2.7Metals & Non-Metals
1.2.8Alkali Metals
1.2.9Alkaline Earth Metals
1.2.10Reactivity of Alkaline Earth Metals
1.2.11Redox
1.2.12Transition Metals
1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange
1.5.2Blood Vessels
1.5.3Atherosclerosis
1.5.4Skeletal Muscle
1.5.5Slow & Fast Twitch Fibres
1.5.6Neurones
1.5.7Speed of Transmission
1.5.8Action Potentials
1.5.9End of Topic Test - Neurones & Action Potentials
1.5.10Synapses
1.5.11Types of Synapse
1.5.12Medical Application
1.5.13End of Topic Test - Synapses
1.5.14Chemical Brain Imbalances
1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System
4.5.2Blood Vessels
4.5.3Blood Transfusion & the ABO Rhesus System
4.5.4The Heart
4.5.5The Cardiac Cycle
4.5.6Cardiac Output
4.5.7Coordination of Heart Action
4.5.8Heart Dissection
4.5.9Controlling Heart Rate
4.5.10Electrocardiograms
4.5.11Cardiovascular Disease
4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency
4.9.2Work & Energy
4.9.3Conservation of Energy
4.9.4Pressure
4.9.5First Law of Thermodynamics
4.9.6Second Law of Thermodynamics
4.9.7Heat Engines, Heat Pumps & Refrigerators
4.9.8Non-Flow Processes
4.9.9p-V Diagrams
4.9.10Ideal Gases
4.9.11Ideal Gases 2
4.9.12Thermal Energy Transfer
4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
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