4.2.3

Electrolysis

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Electrolysis

Electrolysis is the process that splits ionic compounds into their constituent (different) elements (the elements that make them up). Electrolysis happens using a solution that conducts electricity.

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Electrolyte

  • When ionic compounds are melted or dissolved in water, the ions (charged particles that have gained/lost electrons) are free to move around, and the liquid/solution will conduct electricity.
  • Ionic compounds that dissolve in water to make a solution that conducts electricity are called electrolytes.
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Electrodes

  • When a voltage (direct current) is applied across an electrolyte, the charged ions are attracted to the electrode with the opposite charge to the ion.
    • Positively charged ions (cations) move to the negative electrode (cathode).
    • Negatively charged ions (anions) move to the positive electrode (anode).
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Elements

  • When an ion touches an electrode, electrons can be transferred, producing elements.
    • E.g. if copper ions (Cu2+) are in a solution and a voltage is applied, they'll move to the cathode (negative electrode). When they touch the cathode, each Cu2+ ion will gain 2 electrons and form a copper metal.

Electrolysis of Aqueous Solutions

The products of the electrolysis of aqueous solutions are difficult to predict because the water molecules in the solution split up to form hydrogen (H+) and hydroxide (OH-) ions.

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At the anode (positive electrode)

  • What is formed at the anode depends on if halide ions are present:
    • If halide ions are present, the respective halogen forms.
    • If halide ions are absent, oxygen forms.
Illustrative background for At the cathode (negative electrode)Illustrative background for At the cathode (negative electrode) ?? "content

At the cathode (negative electrode)

  • What is formed at the cathode depends on the reactivity of the metal:
    • If the metal's more reactive than hydrogen, hydrogen is produced.
    • If the metal's less reactive than hydrogen, the metal is produced.

Jump to other topics

1Principles of Science I

1.1Structure & Bonding

1.2Properties of Substances

1.3Cell Structure & Function

1.4Cell Specialisation

1.5Tissue Structure & Function

1.6Working with Waves

1.7Waves in Communication

2Practical Scientific Procedures and Techniques

3Science Investigation Skills

4Principles of Science II

4.1Extracting Elements

4.2Relating Properties to use of Substances

4.3Organic Chemistry

4.4Energy Changes in Industry

4.5The Circulatory System

4.6Ventilation & Gas Exchange

4.7Urinary System

4.8Cell Transport

4.9Thermal Physics

4.10Materials

4.11Fluids

5Contemporary Issues in Science

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