4.2.3
Electrolysis
Electrolysis
Electrolysis
Electrolysis is the process that splits ionic compounds into their constituent (different) elements (the elements that make them up). Electrolysis happens using a solution that conducts electricity.


Electrolyte
Electrolyte
- When ionic compounds are melted or dissolved in water, the ions (charged particles that have gained/lost electrons) are free to move around, and the liquid/solution will conduct electricity.
- Ionic compounds that dissolve in water to make a solution that conducts electricity are called electrolytes.


Electrodes
Electrodes
- When a voltage (direct current) is applied across an electrolyte, the charged ions are attracted to the electrode with the opposite charge to the ion.
- Positively charged ions (cations) move to the negative electrode (cathode).
- Negatively charged ions (anions) move to the positive electrode (anode).


Elements
Elements
- When an ion touches an electrode, electrons can be transferred, producing elements.
- E.g. if copper ions (Cu2+) are in a solution and a voltage is applied, they'll move to the cathode (negative electrode). When they touch the cathode, each Cu2+ ion will gain 2 electrons and form a copper metal.
Electrolysis of Aqueous Solutions
Electrolysis of Aqueous Solutions
The products of the electrolysis of aqueous solutions are difficult to predict because the water molecules in the solution split up to form hydrogen (H+) and hydroxide (OH-) ions.


At the anode (positive electrode)
At the anode (positive electrode)
- What is formed at the anode depends on if halide ions are present:
- If halide ions are present, the respective halogen forms.
- If halide ions are absent, oxygen forms.


At the cathode (negative electrode)
At the cathode (negative electrode)
- What is formed at the cathode depends on the reactivity of the metal:
- If the metal's more reactive than hydrogen, hydrogen is produced.
- If the metal's less reactive than hydrogen, the metal is produced.
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model
1.1.2Electron Shells, Sub-Shells & Orbitals
1.1.3Ionic Bonding
1.1.4Representing Ionic Bonds
1.1.5Covalent Bonding
1.1.6Representing Covalent Bonds
1.1.7Metallic Bonding
1.1.8Intermolecular Forces
1.1.9Intermolecular Forces 2
1.1.10End of Topic Test - Bonding
1.1.11Relative Masses
1.1.12The Mole
1.1.13Molar Calculations
1.1.14Molar Calculations 2
1.1.15Empirical & Molecular Formulae
1.1.16Balanced Equations
1.1.17Percentage Yield
1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table
1.2.2Ionisation Energy
1.2.3Factors Affecting Ionisation Energies
1.2.4Trends of Ionisation
1.2.5Trends in the Periodic Table
1.2.6Polarity
1.2.7Metals & Non-Metals
1.2.8Alkali Metals
1.2.9Alkaline Earth Metals
1.2.10Reactivity of Alkaline Earth Metals
1.2.11Redox
1.2.12Transition Metals
1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange
1.5.2Blood Vessels
1.5.3Atherosclerosis
1.5.4Skeletal Muscle
1.5.5Slow & Fast Twitch Fibres
1.5.6Neurones
1.5.7Speed of Transmission
1.5.8Action Potentials
1.5.9End of Topic Test - Neurones & Action Potentials
1.5.10Synapses
1.5.11Types of Synapse
1.5.12Medical Application
1.5.13End of Topic Test - Synapses
1.5.14Chemical Brain Imbalances
1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System
4.5.2Blood Vessels
4.5.3Blood Transfusion & the ABO Rhesus System
4.5.4The Heart
4.5.5The Cardiac Cycle
4.5.6Cardiac Output
4.5.7Coordination of Heart Action
4.5.8Heart Dissection
4.5.9Controlling Heart Rate
4.5.10Electrocardiograms
4.5.11Cardiovascular Disease
4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency
4.9.2Work & Energy
4.9.3Conservation of Energy
4.9.4Pressure
4.9.5First Law of Thermodynamics
4.9.6Second Law of Thermodynamics
4.9.7Heat Engines, Heat Pumps & Refrigerators
4.9.8Non-Flow Processes
4.9.9p-V Diagrams
4.9.10Ideal Gases
4.9.11Ideal Gases 2
4.9.12Thermal Energy Transfer
4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
Jump to other topics
1Principles of Science I
1.1Structure & Bonding
1.1.1Atomic Model
1.1.2Electron Shells, Sub-Shells & Orbitals
1.1.3Ionic Bonding
1.1.4Representing Ionic Bonds
1.1.5Covalent Bonding
1.1.6Representing Covalent Bonds
1.1.7Metallic Bonding
1.1.8Intermolecular Forces
1.1.9Intermolecular Forces 2
1.1.10End of Topic Test - Bonding
1.1.11Relative Masses
1.1.12The Mole
1.1.13Molar Calculations
1.1.14Molar Calculations 2
1.1.15Empirical & Molecular Formulae
1.1.16Balanced Equations
1.1.17Percentage Yield
1.1.18End of Topic Test - Amount of Substance
1.2Properties of Substances
1.2.1The Periodic Table
1.2.2Ionisation Energy
1.2.3Factors Affecting Ionisation Energies
1.2.4Trends of Ionisation
1.2.5Trends in the Periodic Table
1.2.6Polarity
1.2.7Metals & Non-Metals
1.2.8Alkali Metals
1.2.9Alkaline Earth Metals
1.2.10Reactivity of Alkaline Earth Metals
1.2.11Redox
1.2.12Transition Metals
1.2.13Redox Reactions of Transition Metals
1.3Cell Structure & Function
1.4Cell Specialisation
1.5Tissue Structure & Function
1.5.1Human Gas Exchange
1.5.2Blood Vessels
1.5.3Atherosclerosis
1.5.4Skeletal Muscle
1.5.5Slow & Fast Twitch Fibres
1.5.6Neurones
1.5.7Speed of Transmission
1.5.8Action Potentials
1.5.9End of Topic Test - Neurones & Action Potentials
1.5.10Synapses
1.5.11Types of Synapse
1.5.12Medical Application
1.5.13End of Topic Test - Synapses
1.5.14Chemical Brain Imbalances
1.5.15Effect of Drugs on the Brain
1.6Working with Waves
1.7Waves in Communication
2Practical Scientific Procedures and Techniques
3Science Investigation Skills
3.1Scientific Processes
3.2Data Handling & Analysis
3.3Enzymes in Action
3.4Diffusion
3.5Plants & Their Environment
3.6Energy Content in Fuels
4Principles of Science II
4.1Extracting Elements
4.2Relating Properties to use of Substances
4.3Organic Chemistry
4.4Energy Changes in Industry
4.5The Circulatory System
4.5.1The Circulatory System
4.5.2Blood Vessels
4.5.3Blood Transfusion & the ABO Rhesus System
4.5.4The Heart
4.5.5The Cardiac Cycle
4.5.6Cardiac Output
4.5.7Coordination of Heart Action
4.5.8Heart Dissection
4.5.9Controlling Heart Rate
4.5.10Electrocardiograms
4.5.11Cardiovascular Disease
4.5.12Investigating Heart Rates
4.6Ventilation & Gas Exchange
4.7Urinary System
4.9Thermal Physics
4.9.1Power & Efficiency
4.9.2Work & Energy
4.9.3Conservation of Energy
4.9.4Pressure
4.9.5First Law of Thermodynamics
4.9.6Second Law of Thermodynamics
4.9.7Heat Engines, Heat Pumps & Refrigerators
4.9.8Non-Flow Processes
4.9.9p-V Diagrams
4.9.10Ideal Gases
4.9.11Ideal Gases 2
4.9.12Thermal Energy Transfer
4.9.13Thermal Energy Transfer Experiments
4.10Materials
5Contemporary Issues in Science
5.1Contemporary Issues in Science
5.2Analysing Scientific Information
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