Electrolysis - Copper Sulfate
Chemistry: Edexcel IGCSE, topic 7.1.4
Electrolysis of Copper Sulfate
Copper can be purified using electrolysis. You need impure copper attached as the anode.

Copper sulfate electrolysis
- The copper ions (Cu2+) will go into the electrolyte solution of copper sulfate.
- The Cu2+ ions will be attracted to the cathode and pure copper will form.
- Cu2+(aq) + 2e- → Cu(s)

Results
- The impurities of the anode will fall to the bottom of the beaker.
- When the mass of the cathode is constant, the purification process is complete.

Measure mass
To measure the mass of copper formed on the cathode over time:
- Record the initial mass of the electrodes. The cathode must be cleaned for the copper to stick to it
- Use a variable resistor because the current may vary during the process. It should be kept constant.

Measure mass (continued)
- You should wash electrodes to remove any copper sulfate. You should then dry them.
- You should also wash the electrodes with a more volatile solvent to make them dry faster. You could use propanone, for instance.

Equation
- Measure the final mass of the electrodes to work out the change in mass: change in mass = final mass - initial mass.
Test yourself on Electrolysis - Copper Sulfate
What is the purpose of electrolysis of copper sulfate?
Which of these is the correct half equation for copper ions in an electrolysis experiment?