Testing Sulfates 2

Chemistry: Edexcel IGCSE, topic 13.2.10

Testing for Sulfates

Sulfates are compounds that contain SO42− ions. There are two steps to sulfate testing:

Add dilute hydrochloric acid

Add dilute hydrochloric acid

  • Add dilute hydrochloric acid to an unknown solution.
  • This removes carbonate ions. These could disrupt test results by forming a precipitate with the barium ions added in step 2.
Add barium chloride

Add barium chloride

  • Add barium chloride to the same solution.
  • If sulfates are present, the white precipitate barium sulfate will form:
    • Ba2+(aq) + SO42−(aq) → BaSO4(s)

Test yourself on Testing Sulfates 2

  • Why is hydrochloric acid added to an unknown solution when you are testing for a sulfate ion?

  • I test for ions in an unknown solution by adding hydrochloric acid followed by barium chloride. A white precipitate is formed. What can I say about the unknown solution?

  • I test for ions in an unknown solution by adding nitric acid followed by silver nitrate. A cream precipitate is formed. What can I say about the unknown solution?

  • I test for ions in an unknown solution by adding nitric acid followed by silver nitrate. A pale yellow precipitate is formed. What can I say about the unknown solution?

  • I test for ions in an unknown solution by adding barium chloride. A precipitate is formed in the reaction. What can I say about the unknown solution?

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