Electrolysis of Copper Sulfate
Chemistry: Cambridge International GCSE Supplement, topic 4.1.7
Electrolysis of Copper Sulfate
Copper can be purified using electrolysis. You need impure copper attached as the anode.

Copper sulfate electrolysis
- The copper ions (Cu2+) will go into the electrolyte solution of copper sulfate.
- The Cu2+ ions will be attracted to the cathode and pure copper will form.
- Cu2+(aq) + 2e- → Cu(s)

Results
- The impurities of the anode will fall to the bottom of the beaker.
- When the mass of the cathode is constant, the purification process is complete.

Measure mass
To measure the mass of copper formed on the cathode over time:
- Record the initial mass of the electrodes. The cathode must be cleaned for the copper to stick to it
- Use a variable resistor because the current may vary during the process. It should be kept constant.

Measure mass (continued)
- You should wash electrodes to remove any copper sulfate. You should then dry them.
- You should also wash the electrodes with a more volatile solvent to make them dry faster. You could use propanone, for instance.

Equation
- Measure the final mass of the electrodes to work out the change in mass: change in mass = final mass - initial mass.
Test yourself on Electrolysis of Copper Sulfate
What is the purpose of electrolysis of copper sulfate?
Which of these is the correct half equation for copper ions in an electrolysis experiment?