General Formulae of Organic Compounds

Chemistry: Cambridge International GCSE Supplement, topic 11.1.2

General Formulae of Organic Compounds

A homologous series groups organic compounds with similar structure, same functional group, and differ by CH2 units. These include alkanes, alkenes, alcohols, and carboxylic acids.

What is a homologous series?

What is a homologous series?

  • A homologous series is a group of organic compounds.
  • Compounds in a homologous series have similar structures.
  • Each member of the series differs from the next by a -CH2- unit in the chain.
  • Members have the same functional group.
  • Example: Alkanes, alkenes, alcohols, carboxylic acids.
General formula of alkanes (CnH2n+2)

General formula of alkanes (CnH2n+2)

  • Alkanes are saturated hydrocarbons.
  • Alkanes only have carbon and hydrogen.
  • Alkanes have single bonds only.
  • The general formula is CnH2n+2.
General formula of alkenes (CnH2n)

General formula of alkenes (CnH2n)

  • Alkenes are unsaturated hydrocarbons.
  • Alkenes have a double bond between adjacent carbon atoms.
  • The general formula is CnH2n.
  • Alkenes react differently from alkanes due to double bonds.
General formula of alcohols (CnH2n+1OH)

General formula of alcohols (CnH2n+1OH)

  • Alcohols contain an –OH group (hydroxyl).
  • Alcohols have hydrocarbons plus OH.
  • The general formula is CnH2n+1OH.
  • Alcohols can dissolve in water and burn.
General formula of carboxylic acids (CnH2n+1COOH)

General formula of carboxylic acids (CnH2n+1COOH)

  • Carboxylic acids have a –COOH group.
  • They have the functional group carboxyl.
  • The general formula is CnH2n+1COOH.
  • Carboxylic acids taste sour and react with carbonates.

Test yourself on General Formulae of Organic Compounds

  • What is a defining characteristic of compounds within a homologous series?

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