Cracking

Chemistry: Cambridge International GCSE Supplement, topic 11.5.5

Cracking

Cracking is the process that breaks down long-chain hydrocarbons into shorter-chain molecules that have a higher commercial value. Cracking is an example of a thermal decomposition reaction. Cracking can be done in two ways:

Catalytic cracking

Catalytic cracking

  • Vapourised heavy hydrocarbons are passed over the top of a heated catalyst.
  • Alkanes and alkenes are produced by this reaction.
  • E.g. hexane → butane + ethene
Steam cracking

Steam cracking

  • Vapourised heavy hydrocarbons are mixed with steam in a high temperature environment.
  • The products include alkanes and alkenes.
  • E.g. decane → octane + ethene

Test yourself on Cracking

  • Methods of cracking hydrocarbons

  • What type of chemical reaction is cracking?

  • In which method of cracking are vapourised heavy hydrocarbons passed over a hot catalyst?

  • What are the products of cracking?

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