4.2.5
Thermodynamics & Kinetic Control
After reading these notes, test your knowledge with free interactive questions on Seneca — used by over 10 million students.
Thermodynamic & Kinetic Control
Reactions proceed due to a combination of favorable kinetics and thermodynamics. If one of these factors hinders the progression of a reaction, it is said to be controlling.
Thermodynamic control
- If there is enough energy in the system for the activation energy to be reached but the reaction does not proceed, then it is said to be under thermodynamic control.
- This means that it is not thermodynamically favorable for the reaction to proceed.
Examples of thermodynamic control
- A simple example is trying to use a stone as fuel for a fire. The fire provides more than enough energy for activation but it is not thermodynamically favorable for the stone to react with oxygen.
Kinetic control
- Kinetic control occurs when a reaction does not occur at a measurable rate despite being thermodynamically favorable.
- This is not because the position of equilibrium is to the left because the thermodynamics would favor a position to the right.
- The reason is that there is not sufficient energy to overcome the activation energy.
Examples of kinetic control
- Fossil fuels react with oxygen when they burn. These reactions are very thermodynamically favored, both enthalpically and entropically.
- So why does coal or oil or natural gas not spontaneously combust?
- There is not sufficient energy to start the reaction.
- In most cases, some sort of spark or fire is required to provide the activation energy.
1Structure - Models of the Particulate of Matter
1.1Introduction to the Particulate Model of Matter
1.2The Nuclear Atom
1.3Electron Configuration
1.4Counting Particles by Mass: The Mole
1.6Elements, Compounds & Mixtures
1.7States of Matter & Changes of State
1.8Reacting Masses &. Volumes
1.9Solutions
2Structure - Models of Bonding & Structure
2.1The Ionic Model
2.2The Covalent Model
2.3Covalent Structures
2.4The Metallic Model
2.5From Models to Materials
2.6Valence Electrons & Ionic Compounds
2.7Molecular Shape
3Structure - Classification of Matter
3.1The Periodic Table: Classification of Elements
3.2Periodic Trends
3.3Group 1 Alkali Metals
3.4Halogens
3.5Noble gases, group 18
3.6Functional Groups: Classification of Organic
3.7Functional Group Chemistry
3.8Alkanes
3.9Alcohols
4Reactivity - What Drives Chemical Reaction?
4.1Endothermic & Exothermic Reactions
4.2Enthalpy of Reaction, Formation, & Hess' Law
5Reactivity - How Much, How Fast & How Far?
5.1Kinetics
5.2Rates of Reaction
5.3Stoichometry
5.4Le Châtelier’s Principle
5.5Introduction to Equilibrium
5.6Equilibrium Constant
5.7Reaction Quotient & Equilibrium Constant
6Reactivity - The Mechanisms of Chemical Change
6.1Proton Transfer Reactions
6.2The pH Scale
6.3Strong & Weak Acids and Bases
6.4Acid Deposition
6.5Types of Organic Reactions
6.6Oxidation & Reduction
6.7Electrochemical Cells
6.9Acid-Base Titrations
6.9.1Titration Calculation Weak Acid & Strong Base6.9.2Titration Experimental Detail6.9.3Extended Response - Titration6.9.4Titration Calculations6.9.5Titration Curves6.9.6Titration Calculation Strong Acid & Weak Base6.9.7IB Multiple Choice - Titrations6.9.8Polyprotic Acids6.9.9Titration Calculations Strong Acid & Strong Base6.9.10Titrations Curves 2
7Measurement, Data Processing & Analysis
7.1Uncertainties & Errors in Measurements & Results
7.2Graphical Techniques
7.3Spectroscopic Identification of Organic Compounds
7.4Infrared Spectroscpy
Jump to other topics
1Structure - Models of the Particulate of Matter
1.1Introduction to the Particulate Model of Matter
1.2The Nuclear Atom
1.3Electron Configuration
1.4Counting Particles by Mass: The Mole
1.6Elements, Compounds & Mixtures
1.7States of Matter & Changes of State
1.8Reacting Masses &. Volumes
1.9Solutions
2Structure - Models of Bonding & Structure
2.1The Ionic Model
2.2The Covalent Model
2.3Covalent Structures
2.4The Metallic Model
2.5From Models to Materials
2.6Valence Electrons & Ionic Compounds
2.7Molecular Shape
3Structure - Classification of Matter
3.1The Periodic Table: Classification of Elements
3.2Periodic Trends
3.3Group 1 Alkali Metals
3.4Halogens
3.5Noble gases, group 18
3.6Functional Groups: Classification of Organic
3.7Functional Group Chemistry
3.8Alkanes
3.9Alcohols
4Reactivity - What Drives Chemical Reaction?
4.1Endothermic & Exothermic Reactions
4.2Enthalpy of Reaction, Formation, & Hess' Law
5Reactivity - How Much, How Fast & How Far?
5.1Kinetics
5.2Rates of Reaction
5.3Stoichometry
5.4Le Châtelier’s Principle
5.5Introduction to Equilibrium
5.6Equilibrium Constant
5.7Reaction Quotient & Equilibrium Constant
6Reactivity - The Mechanisms of Chemical Change
6.1Proton Transfer Reactions
6.2The pH Scale
6.3Strong & Weak Acids and Bases
6.4Acid Deposition
6.5Types of Organic Reactions
6.6Oxidation & Reduction
6.7Electrochemical Cells
6.9Acid-Base Titrations
6.9.1Titration Calculation Weak Acid & Strong Base6.9.2Titration Experimental Detail6.9.3Extended Response - Titration6.9.4Titration Calculations6.9.5Titration Curves6.9.6Titration Calculation Strong Acid & Weak Base6.9.7IB Multiple Choice - Titrations6.9.8Polyprotic Acids6.9.9Titration Calculations Strong Acid & Strong Base6.9.10Titrations Curves 2
7Measurement, Data Processing & Analysis
7.1Uncertainties & Errors in Measurements & Results
7.2Graphical Techniques
7.3Spectroscopic Identification of Organic Compounds
7.4Infrared Spectroscpy
Practice questions on Thermodynamics & Kinetic Control
Can you answer these? Test yourself with free interactive practice on Seneca — used by over 10 million students.
- 1When is a reaction under kinetic control? Multiple choice
Unlock your full potential with Seneca Premium
Unlimited access to 10,000+ open-ended exam questions
Mini-mock exams based on your study history
Unlock 800+ premium courses & e-books