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Molar Calculations of Solutions

We can calculate the number of moles of a liquid or solution using the volume and concentration.

Heterogenous vs homogenous

Heterogenous vs homogenous

  • Solutions are sometimes known as homogenous mixtures and can be liquid, solid, or gas.
    • In solutions, the constituents have the same proportions throughout the sample, so the macroscopic properties of the solution are consistent throughout.
  • Heterogeneous mixtures have a non-uniform composition and the macroscopic properties vary depending on the constituents.
    • In heterogeneous mixtures, you can separate the individual components. An example would be a cup of water with gravel in.
Liquid solutions

Liquid solutions

  • Liquid solutions can be represented in a variety of ways. The most common way in a laboratory is "molarity".
  • It's much easier to look at a liquid and measure its volume than to evaporate any water and measure the mass of the remaining solid.
    • So we need a value that will let us know how much of a solid is dissolved in a solution simply from its volume.
  • If we know the concentration of a solution, we can calculate the number of moles in any sample volume of the solution.
The equation

The equation

  • Molarity is defined as moles per unit volume. The usual units of molarity are moles per liter (L).
  • So moles per liter is mol ÷ L.
    • This is often written as mol L -1 or just "M".
  • Molarity is sometimes written as moldm -3, where 1 L = 1 L. (Same thing, just different units!)
Diagram
An example

An example

  • Three moles of NaCl are dissolved in half a liter of water.
    • Molarity = number of moles ÷ volume
    • Molarity = 3 mol ÷ 0.5 L
    • Molarity = 6 mol/L or 6 M
Jump to other topics
1

Structure - Models of the Particulate of Matter

2

Structure - Models of Bonding & Structure

3

Structure - Classification of Matter

3.1

The Periodic Table: Classification of Elements

3.2

Periodic Trends

3.3

Group 1 Alkali Metals

3.4

Halogens

3.5

Noble gases, group 18

3.6

Functional Groups: Classification of Organic

3.7

Functional Group Chemistry

3.8

Alkanes

3.9

Alcohols

3.10

Halogenoalkanes

4

Reactivity - What Drives Chemical Reaction?

5

Reactivity - How Much, How Fast & How Far?

6

Reactivity - The Mechanisms of Chemical Change

7

Measurement, Data Processing & Analysis

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