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Valence Shell Electron-Pair Repulsion (VSEPR) Theory

The final geometry of a covalent molecule depends on the number and type of electron domains around a central atom.

Electron domains

Electron domains

  • Electrons are attracted to and constrained around positive nuclei in electron domains.
  • When determining covalent molecular geometries, the repulsion between electron domains (electron pairs) around a central atom needs to be considered.
  • These electron domains repel each other until the repulsive forces are minimised to give an optimised geometry.
VSEPR theory

VSEPR theory

  • The final geometry of a covalent molecule depends on:
    • The number of electron domains
    • The identity of these electron domains (non-bonding vs. bonding)
  • Considering these effects when determining the molecular shape and bond angles of a molecule is called Valence-Shell Electron-Pair Repulsion (VSEPR) theory.

Electron Domain and Molecular Geometries

A summary of how the number and type of electron domains relate to the electron domain and molecular geometries is shown below:

Linear

Linear

  • Total electron domains: 2
    • bonding domains: 2
    • non-bonding domains: 0
  • Electron domain geometry: Linear
  • Molecular geometry: Linear
  • Bond angle: 180°
Trigonal planar

Trigonal planar

  • Total electron domains: 3
    • bonding domains: 3
    • non-bonding domains: 0
  • Electron domain geometry: Trigonal planar
  • Molecular geometry: Trigonal planar
  • Bond angle: 120°
Trigonal planar - bent

Trigonal planar - bent

  • Total electron domains: 3
    • bonding domains: 2
    • non-bonding domains: 1
  • Electron domain geometry: Trigonal planar
  • Molecular geometry: Bent
Tetrahedral

Tetrahedral

  • Total electron domains: 4
    • bonding domains: 4
    • non-bonding domains: 0
  • Electron domain geometry: Tetrahedral
  • Molecular geometry: Tetrahedral
  • Bond angle: 109.5°
Tetrahedral - trigonal pyramidal

Tetrahedral - trigonal pyramidal

  • Total electron domains: 4
    • bonding domains: 3
    • non-bonding domains: 1
  • Electron domain geometry: Tetrahedral
  • Molecular geometry: Trigonal pyramidal
Tetrahedral - bent

Tetrahedral - bent

  • Total electron domains: 4
    • bonding domains: 2
    • non-bonding domains: 2
  • Electron domain geometry: Tetrahedral
  • Molecular geometry: Bent

Types of Bonding Domains

When considering molecular geometry, the type of electron domains present needs to be considered.

Bonding and non-bonding domains

Bonding and non-bonding domains

  • Electron domains can be either bonding or non-bonding.
  • Non-bonding domains (lone pairs) are attracted to only one nucleus, whereas a bonding domain is attracted to two nuclei.
  • The attraction of a bonding domain (bonding pair) by two nuclei causes the orbital to elongate and occupy less space around each nucleus compared to non-bonding domains.
  • Therefore, non-bonding electron domains repel more than bonding domains and inflict wider angles in molecular geometries.
Example

Example

  • This effect is summarised well by comparing the different molecular structures of methane (CH4), ammonia (NH3), and water (H2O), which all have four electron domains.
Jump to other topics
1

Structure - Models of the Particulate of Matter

2

Structure - Models of Bonding & Structure

3

Structure - Classification of Matter

3.1

The Periodic Table: Classification of Elements

3.2

Periodic Trends

3.3

Group 1 Alkali Metals

3.4

Halogens

3.5

Noble gases, group 18

3.6

Functional Groups: Classification of Organic

3.7

Functional Group Chemistry

3.8

Alkanes

3.9

Alcohols

3.10

Halogenoalkanes

4

Reactivity - What Drives Chemical Reaction?

5

Reactivity - How Much, How Fast & How Far?

6

Reactivity - The Mechanisms of Chemical Change

7

Measurement, Data Processing & Analysis

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