9.4.1

Metals - Reactivity Series & Reactivity

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Metals - Reactivity Series and Reactivity

The reactivity series orders metals from potassium to gold. Higher metals react vigorously with water or steam and acids, displacing hydrogen.

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The reactivity series order

  • The reactivity series orders metals by their reactivity.
    • The order is: potassium, sodium, calcium, magnesium, aluminium, carbon, zinc, iron, hydrogen, copper, silver, gold.
  • Potassium is the most reactive metal in this series.
  • Gold is the least reactive metal.
  • Carbon is included to compare with metals in extractions.
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Reactions with cold water

  • Potassium reacts very quickly with cold water, producing hydrogen gas and potassium hydroxide.
  • Sodium reacts rapidly with cold water, producing sodium hydroxide and hydrogen gas.
    • 2Na + 2H₂O → 2NaOH + H₂
  • Calcium reacts slowly with cold water forming calcium hydroxide and hydrogen gas.
    • These reactions demonstrate how metals higher in the reactivity series react more vigorously.
    • Reactions like these release hydrogen gas, which can be seen bubbling.
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Magnesium reaction with steam

  • Magnesium does not react quickly with cold water but reacts with steam.
  • Magnesium reacts with steam to produce magnesium oxide and hydrogen gas.
    • This shows magnesium is less reactive than calcium but still reacts with water in steam form.
  • Magnesium must be heated to react with water as steam.
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Reactivity with dilute hydrochloric acid

  • Magnesium reacts rapidly with dilute hydrochloric acid, producing magnesium chloride and hydrogen gas.
  • Zinc and iron react with dilute hydrochloric acid slowly, producing zinc chloride, iron chloride, and hydrogen gas.
  • Copper, silver, and gold do not react with dilute hydrochloric acid.
    • The reactivity decreases down the series, metals below hydrogen do not react with acids.
  • Metal reactivity relates directly to whether the metal displaces hydrogen from acid.
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Summary and explanation

  • The reactivity series shows how easily metals lose electrons and react.
  • Metals higher in the series lose electrons easily, reacting strongly with water and acids.
  • Metals below hydrogen in the series do not react with dilute acids.
  • This chemical behaviour helps decide how metals are extracted and used.

Jump to other topics

1States of Matter

2Atoms, Elements & Compounds

3Stoichometry

4Electrochemistry

5Chemical Energetics

6Chemical Reactions

7Acids, Bases & Salts

8The Periodic Table

9Metals

10Chemistry of the Environment

11Organic Chemistry

11.1Formulae, Functional Groups & Terminology

11.2Naming Organic Compounds

11.3Fuels

11.4Alkanes

11.5Alkenes

11.6Alcohols

11.7Carboxylic Acids

11.8Polymers

12Experimental Techniques & Chemical Analysis

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