9.4.1

Metals - Reactivity Series & Reactivity

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Metals - Reactivity Series and Reactivity

The reactivity series orders metals from potassium to gold. Higher metals react vigorously with water or steam and acids, displacing hydrogen.

The reactivity series order

The reactivity series order

  • The reactivity series orders metals by their reactivity.
    • The order is: potassium, sodium, calcium, magnesium, aluminium, carbon, zinc, iron, hydrogen, copper, silver, gold.
  • Potassium is the most reactive metal in this series.
  • Gold is the least reactive metal.
  • Carbon is included to compare with metals in extractions.
Reactions with cold water

Reactions with cold water

  • Potassium reacts very quickly with cold water, producing hydrogen gas and potassium hydroxide.
  • Sodium reacts rapidly with cold water, producing sodium hydroxide and hydrogen gas.
    • 2Na + 2H₂O → 2NaOH + H₂
  • Calcium reacts slowly with cold water forming calcium hydroxide and hydrogen gas.
    • These reactions demonstrate how metals higher in the reactivity series react more vigorously.
    • Reactions like these release hydrogen gas, which can be seen bubbling.
Magnesium reaction with steam

Magnesium reaction with steam

  • Magnesium does not react quickly with cold water but reacts with steam.
  • Magnesium reacts with steam to produce magnesium oxide and hydrogen gas.
    • This shows magnesium is less reactive than calcium but still reacts with water in steam form.
  • Magnesium must be heated to react with water as steam.
Reactivity with dilute hydrochloric acid

Reactivity with dilute hydrochloric acid

  • Magnesium reacts rapidly with dilute hydrochloric acid, producing magnesium chloride and hydrogen gas.
  • Zinc and iron react with dilute hydrochloric acid slowly, producing zinc chloride, iron chloride, and hydrogen gas.
  • Copper, silver, and gold do not react with dilute hydrochloric acid.
    • The reactivity decreases down the series, metals below hydrogen do not react with acids.
  • Metal reactivity relates directly to whether the metal displaces hydrogen from acid.
Summary and explanation

Summary and explanation

  • The reactivity series shows how easily metals lose electrons and react.
  • Metals higher in the series lose electrons easily, reacting strongly with water and acids.
  • Metals below hydrogen in the series do not react with dilute acids.
  • This chemical behaviour helps decide how metals are extracted and used.
Jump to other topics
1

States of Matter

2

Atoms, Elements & Compounds

3

Stoichometry

4

Electrochemistry

5

Chemical Energetics

6

Chemical Reactions

7

Acids, Bases & Salts

8

The Periodic Table

9

Metals

10

Chemistry of the Environment

11

Organic Chemistry

11.1

Formulae, Functional Groups & Terminology

11.2

Naming Organic Compounds

11.3

Fuels

11.4

Alkanes

11.5

Alkenes

11.6

Alcohols

11.7

Carboxylic Acids

11.8

Polymers

12

Experimental Techniques & Chemical Analysis

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