11.2.3

Naming Unbranched Esters from Alcohols & Acids

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Naming Unbranched Esters from Alcohols and Carboxylic Acids

Esters form from alcohols (-ol) and carboxylic acids (-anoic acid). Named as alkyl + oate, they contain a C=O and C-O-C link. Displayed formulae show these structures.

What are esters?

What are esters?

  • Esters are organic compounds made from alcohols and carboxylic acids.
    • Esters contain a carbon atom double-bonded to oxygen and single-bonded to another oxygen atom.
  • The other oxygen is linked to an alkyl group from the alcohol.
Naming unbranched alcohols

Naming unbranched alcohols

  • Unbranched alcohols have a straight chain of carbon atoms.
    • Alcohol names end with "-ol"
    • Examples include methanol (1 carbon), ethanol (2 carbons), propanol (3 carbons), butanol (4 carbons).
  • Each name shows the number of carbons in the chain.
Naming unbranched carboxylic acids

Naming unbranched carboxylic acids

  • Unbranched carboxylic acids have a straight chain ending in COOH.
    • Acid names end with "-anoic acid."
    • Examples include methanoic acid, ethanoic acid, propanoic acid, butanoic acid.
  • These acids have 1 to 4 carbon atoms in the chain.
Naming esters formed from alcohols and acids

Naming esters formed from alcohols and acids

  • Esters are named: alkyl group from alcohol + acid name with "-oate" ending.
    • For example, ethanol + ethanoic acid → ethyl ethanoate.
  • The alkyl group name comes from the alcohol; the acid name changes "-anoic acid" to "-anoate".
  • This rule applies to esters with up to 4 carbons in each part.
Drawing displayed formulae of unbranched esters

Drawing displayed formulae of unbranched esters

  • To draw esters, link the alcohol alkyl group (C and H atoms) to the ester oxygen.
    • Attach the acid part with a carbon double-bonded to oxygen and single-bonded to ester oxygen.
    • For example, ethyl ethanoate has a 2-carbon group attached to oxygen and the acid part with 2 carbons.
  • Practice drawing all combinations from 1 to 4 carbons on each part.
Jump to other topics
1

States of Matter

2

Atoms, Elements & Compounds

3

Stoichometry

4

Electrochemistry

5

Chemical Energetics

6

Chemical Reactions

7

Acids, Bases & Salts

8

The Periodic Table

9

Metals

10

Chemistry of the Environment

11

Organic Chemistry

11.1

Formulae, Functional Groups & Terminology

11.2

Naming Organic Compounds

11.3

Fuels

11.4

Alkanes

11.5

Alkenes

11.6

Alcohols

11.7

Carboxylic Acids

11.8

Polymers

12

Experimental Techniques & Chemical Analysis

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