Cyclic Photophosphorylation
Biology: AQA A Level, topic 5.1.4
Cyclic Photophosphorylation
There are two types of photophosphorylation that take place during the light-dependent reaction: cyclic and non-cyclic photophosphorylation. Here, we will look at cyclic photophosphorylation.

Absorption of light by PSI
- Cyclic photophosphorylation only involves PSI.
- The process is initiated when light energy is absorbed by PSI.
- Light energy excites electrons in the chlorophyll of PSI and the electrons are moved to a higher energy level (they are high-energy electrons).
- This is photoionisation of chlorophyll.

Electron transport chain
- High-energy electrons are released from the chlorophyll and transferred to an electron carrier.
- The electrons are transferred along a chain of electron carriers in the electron transport chain (ETC).
- Unlike in non-cyclic photophosphorylation, the electrons are not transferred from PSII to PSI.
- Instead the electrons cycle continuously through the electron carriers to PSI.

The proton gradient
- As the electrons move down the ETC, they lose energy.
- This energy pumps protons from the stroma into the thylakoids.
- This is the same as in non-cyclic photophosphorylation.
- As protons build up inside the thylakoids, a proton gradient forms across the thylakoid membrane.

Chemiosmosis
- The protons diffuse down the concentration gradient across the thylakoid membrane through the ATP synthase enzyme.
- As protons diffuse through the ATP synthase, energy is released.
- This energy converts ADP and inorganic phosphate to ATP.
- This process is called chemiosmosis.

Comparing cyclic and non-cyclic
- In cyclic photophosphorylation:
- ATP is produced.
- No reduced NADP is produced.
- Electrons are continuously recycled.
- Photolysis does not take place.
- In non-cyclic photophosphorylation:
- ATP and reduced NADP are produced.
- Electrons in PSII are replaced by photolysis.
Test yourself on Cyclic Photophosphorylation
Which photosystem is only involved in cyclic photophosphorylation?
Which of these processes does NOT take place during cyclic photophosphorylation?