1.1.1
Relative Masses
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Relative Atomic Mass
Relative atomic mass (Ar) is the average mass of an element compared to one-twelfth the mass of a single carbon-12 atom.
 1.1.3.2 - Rutherford and Bohr_s atomic structure,h_400,q_80,w_640.png)
What does this mean?
- 1amu is defined as one-twelfth of the mass of a single carbon-12 atom.
- So Ar is the average mass of an element in units of amu.
 1.1.3.2 - Rutherford and Bohr_s atomic structure,h_400,q_80,w_640.png)
What is the average mass?
- Almost every element has multiple stable isotopes.
- This means that some atoms of an element will weigh more than others.
- The average mass is the average of the masses of the elements, weighted according to their abundance.
- E.g. 35Cl is 75% abundant and 37Cl is 25% abundant.
- Ar = (0.75 × 35) + (0.25 × 37) = 35.5
- E.g. 35Cl is 75% abundant and 37Cl is 25% abundant.
Relative Molecular Mass
Relative molecular mass (Mr) is the average mass of a molecule compared to one-twelfth the mass of a single carbon-12 atom.

What does this mean?
- 1amu is defined as one-twelfth of the mass of a single carbon-12 atom.
- So Mr is the average mass of a molecule in the units of amu.

What is the average mass?
- Recall that the Ar takes into account the differences in mass and abundance of isotopes.
- This means that we can simply add the Ar values for all the atoms in a molecule to calculate the Mr!

Relative formula mass
- The relative formula mass is similar to the relative molecular mass. It even uses the same symbol - Mr!
- It is used when considering ionic compounds.
- Ionic compounds form giant ionic lattices, so we must consider the formula mass. Ionic compounds don't make compounds.
- The relative formula mass is calculated the same way as the Mr. Simply add the Ar values of the ions.
- For example the relative formula mass of NaCl would be 23 (Ar of Na + 35.5 (Ar of Cl) = 58.5.
1Physical Chemistry
1.1Atoms, Molecules & Stoichiometry
1.2Atomic Structure
1.2.1Fundamental Particles1.2.2Isotopes & Mass Number1.2.3Electron Shells, Sub-Shells & Orbitals1.2.4Electron Configuration1.2.5Ionisation Energy1.2.6Factors Affecting Ionisation Energies1.2.7Trends of Ionisation1.2.8Specific Impacts on Ionisation Energies1.2.9Electron Affinity1.2.10End of Topic Test - Atomic Structure1.2.11A-A* (AO2/3) - Atomic Structure
1.3Chemical Bonding
1.3.1Ionic Bonding1.3.2Covalent & Dative Bonding1.3.3Shapes of Molecules1.3.4Intermolecular Forces1.3.5Intermolecular Forces 21.3.6Electronegativity1.3.7Bond Length, Bond Energy, & Bond Polarity1.3.8Metallic Bonding1.3.9Physical Properties1.3.10End of Topic Test - Bonding1.3.11A-A* (AO2/3) - Bonding
1.4States of Matter
1.5Chemical Energetics
1.6Electrochemistry
1.7Equilibria
1.7.1Dynamic Equilibrium & Le Chatelier1.7.2Kc1.7.3Kp1.7.4pH1.7.5The Ionic Product of Water1.7.6Weak Acids & Bases1.7.7Introduction to Solubility Equilibria1.7.8Solubility Equilibria Calculations1.7.9Free Energy of Dissolution1.7.10pH and Solubility1.7.11Common-Ion Effect1.7.12End of Topic Test - Kp & Electrochemistry1.7.13A-A* (AO2/3) - Electrochemical Cells
1.8Partition Coefficient
1.9Reaction Kinetics
1.9.1Collision Theory1.9.2Orders, Rate Constants & Equations1.9.3Rate Graphs1.9.4Rate Determining Step1.9.5Maxwell-Boltzmann Distribution1.9.6Catalysts1.9.7Homogeneous Catalysts1.9.8Heterogeneous Catalysts1.9.9End of Topic Test - Kinetics1.9.10End of Topic Test - Rate Equations1.9.11A-A* (AO2/3) - Rate Equations
2Inorganic Chemistry
2.1The Periodic Table
2.2Group 2
2.3Group 17
2.4Transition Metals
3Organic Chemistry & Analysis
3.1Introduction to Organic Chemistry
3.2Hydrocarbons
3.2.1Fractional Distillation3.2.2Cracking3.2.3Combustion3.2.4Chlorination3.2.5End of Topic Test - Alkanes3.2.6Introduction to Alkenes3.2.7Reactions of Alkenes3.2.8Polymerisation Reactions3.2.9End of Topic Test - Alkenes3.2.10Arenes3.2.11Evidence for Structure of Arenes3.2.12Reactions of Benzene3.2.13End of Topic Test -Arenes
3.3Halogen Derivatives
3.4Hydroxy Compounds
3.5Carbonyl Compounds
3.6Carboxylic Acids & Derivatives
3.7Nitrogen Compounds
3.8Polymerisation
3.9Analytical Techniques
3.9.1Chromatography3.9.2High-Performance Liquid Chromatography3.9.3Gas Chromatography3.9.4IR Spectroscopy3.9.5Uses of IR Spectroscopy3.9.6Mass Spectrometry3.9.7Mass Spectrometry Analysis3.9.8Nuclear Magnetic Resonance3.9.9Carbon-13 NMR3.9.10Proton NMR I3.9.11Proton NMR II3.9.12End of Topic Test - Analytical Techniques3.9.13A-A* (AO2/3) - Analytical Techniques
Jump to other topics
1Physical Chemistry
1.1Atoms, Molecules & Stoichiometry
1.2Atomic Structure
1.2.1Fundamental Particles1.2.2Isotopes & Mass Number1.2.3Electron Shells, Sub-Shells & Orbitals1.2.4Electron Configuration1.2.5Ionisation Energy1.2.6Factors Affecting Ionisation Energies1.2.7Trends of Ionisation1.2.8Specific Impacts on Ionisation Energies1.2.9Electron Affinity1.2.10End of Topic Test - Atomic Structure1.2.11A-A* (AO2/3) - Atomic Structure
1.3Chemical Bonding
1.3.1Ionic Bonding1.3.2Covalent & Dative Bonding1.3.3Shapes of Molecules1.3.4Intermolecular Forces1.3.5Intermolecular Forces 21.3.6Electronegativity1.3.7Bond Length, Bond Energy, & Bond Polarity1.3.8Metallic Bonding1.3.9Physical Properties1.3.10End of Topic Test - Bonding1.3.11A-A* (AO2/3) - Bonding
1.4States of Matter
1.5Chemical Energetics
1.6Electrochemistry
1.7Equilibria
1.7.1Dynamic Equilibrium & Le Chatelier1.7.2Kc1.7.3Kp1.7.4pH1.7.5The Ionic Product of Water1.7.6Weak Acids & Bases1.7.7Introduction to Solubility Equilibria1.7.8Solubility Equilibria Calculations1.7.9Free Energy of Dissolution1.7.10pH and Solubility1.7.11Common-Ion Effect1.7.12End of Topic Test - Kp & Electrochemistry1.7.13A-A* (AO2/3) - Electrochemical Cells
1.8Partition Coefficient
1.9Reaction Kinetics
1.9.1Collision Theory1.9.2Orders, Rate Constants & Equations1.9.3Rate Graphs1.9.4Rate Determining Step1.9.5Maxwell-Boltzmann Distribution1.9.6Catalysts1.9.7Homogeneous Catalysts1.9.8Heterogeneous Catalysts1.9.9End of Topic Test - Kinetics1.9.10End of Topic Test - Rate Equations1.9.11A-A* (AO2/3) - Rate Equations
2Inorganic Chemistry
2.1The Periodic Table
2.2Group 2
2.3Group 17
2.4Transition Metals
3Organic Chemistry & Analysis
3.1Introduction to Organic Chemistry
3.2Hydrocarbons
3.2.1Fractional Distillation3.2.2Cracking3.2.3Combustion3.2.4Chlorination3.2.5End of Topic Test - Alkanes3.2.6Introduction to Alkenes3.2.7Reactions of Alkenes3.2.8Polymerisation Reactions3.2.9End of Topic Test - Alkenes3.2.10Arenes3.2.11Evidence for Structure of Arenes3.2.12Reactions of Benzene3.2.13End of Topic Test -Arenes
3.3Halogen Derivatives
3.4Hydroxy Compounds
3.5Carbonyl Compounds
3.6Carboxylic Acids & Derivatives
3.7Nitrogen Compounds
3.8Polymerisation
3.9Analytical Techniques
3.9.1Chromatography3.9.2High-Performance Liquid Chromatography3.9.3Gas Chromatography3.9.4IR Spectroscopy3.9.5Uses of IR Spectroscopy3.9.6Mass Spectrometry3.9.7Mass Spectrometry Analysis3.9.8Nuclear Magnetic Resonance3.9.9Carbon-13 NMR3.9.10Proton NMR I3.9.11Proton NMR II3.9.12End of Topic Test - Analytical Techniques3.9.13A-A* (AO2/3) - Analytical Techniques
Practice questions on Relative Masses
Can you answer these? Test yourself with free interactive practice on Seneca — used by over 10 million students.
- 1What is an amu?Multiple choice
- 2Relative atomic mass:True / false
- 3Properties of relative molecular mass:True / false
- 4When calculating M<sub>r</sub> you must:Multiple choice
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