2.1.6

Dots-And-Cross Diagrams

Test yourself

Dot-and-Cross Diagrams

Dot-and-cross diagrams can show electrons being transferred and ions being formed. Dots represent electrons from 1 atom and crosses represent electrons from the other atom. Square brackets and a charge (e.g. 2+) represent ions.

Illustrative background for How is sodium fluoride formed?Illustrative background for How is sodium fluoride formed? ?? "content

How is sodium fluoride formed?

  • The sodium atom transfers its outer electron to the fluorine atom, creating Na+ and F- ions. Both of these ions have full outer shells.
Illustrative background for How is calcium oxide formed?Illustrative background for How is calcium oxide formed? ?? "content

How is calcium oxide formed?

  • The calcium atom transfers its 2 outer electrons to the oxygen atom, creating Ca2+ and O2- ions which both have full outer shells.

Dot-and-Cross Diagrams

Dot-and-cross diagrams can be used to represent covalent bonds and to show the sharing of electron pairs.

Illustrative background for Chlorine (Cl<sub>2</sub>)Illustrative background for Chlorine (Cl<sub>2</sub>) ?? "content

Chlorine (Cl2)

  • Each chlorine (Cl) atom begins with 7 electrons in its outer shell.
  • By sharing 1 pair of electrons in a single covalent bond, each Cl atom obtains a full outer shell with 8 electrons.
Illustrative background for Water (H<sub>2</sub>O)Illustrative background for Water (H<sub>2</sub>O) ?? "content

Water (H2O)

  • Because oxygen has 6 electrons in its outer shell, it needs to have 2 extra electrons shared with it to get a full outer electron shell.
  • To do this, it forms a single covalent bond with 2 hydrogen atoms.
Illustrative background for Double and triple bondsIllustrative background for Double and triple bonds ?? "content

Double and triple bonds

  • The earlier examples show single covalent bonds (1 shared pair of electrons between atoms), but it is also possible to form double (2 shared pairs) and even triple covalent bonds (3 shared pairs).
  • Double and triple bonds are normally stronger and require more energy to break.
Illustrative background for Oxygen (O<sub>2</sub>)Illustrative background for Oxygen (O<sub>2</sub>) ?? "content

Oxygen (O2)

  • Each oxygen needs 2 electrons to get a full outer shell.
  • So, each oxygen atom shares 2 electrons with the other, leaving 2 pairs of electrons in the shared space between the atoms.
  • This is an example of a double covalent bond.

Jump to other topics

1Atomic Structure

2Chemical Bonding

3Quantitative Chemistry

4Chemical Changes

5Energy Changes

6The Rate & Extent of Chemical Change

7Organic Chemistry

8Chemical Analysis

9Chemistry of the Atmosphere

10Using Resources

Go student ad image

Unlock your full potential with GoStudent tutoring

  • Affordable 1:1 tutoring from the comfort of your home

  • Tutors are matched to your specific learning needs

  • 30+ school subjects covered

Book a free trial lesson