5.3.4

Wave-Particle Duality

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Wave-Particle Duality - Light

Interference and diffraction show that light is a wave. The photoelectric effect shows that light must be a particle. Quantum physics means light can be both a wave and a particle at the same time.

Light as a wave

Light as a wave

  • Experiments such as shining light through a diffraction grating show us that light must be a wave.
  • Light must diffract through the grating and then interfere constructively and destructively to produce bands of light and dark.
    • Only a wave would be able to do this.
    • A classical particle (e.g. a tennis ball) cannot interfere with another tennis ball to produce one larger one!
Light as a particle

Light as a particle

  • The photoelectric effect displays that light must be a particle.
  • The experiment shows that light particles (photons) have a one-on-one interaction with an electron on the metal surface.

Particle Duality

In 1924, physicist Louis de Broglie suggested that particles might exhibit wave properties, such as diffraction. At the time, scientists dismissed his theory. But electron diffraction and other experiments showed de Broglie was right.

De Broglie wavelength

De Broglie wavelength

  • De Broglie suggested that any particle with a momentum, mv, must have an associated wavelength, λ, given by:
    • λ=hmv\lambda = \frac{h}{mv}
Electron diffraction experiments

Electron diffraction experiments

  • After de Broglie came up with this theory, other scientists set up experiments trying to prove (or disprove) his equation.
  • These experiments showed that electrons did diffract like waves through a grating, and had a wavelength equal to what de Broglie had suggested.
    • Given this experimental evidence, scientists changed their minds and accepted de Broglie's theory.

Electron Orbitals

Electrons can exist only in locations where they interfere constructively.

Electron orbits

Electron orbits

  • How does this affect electrons in atomic orbits?
  • When an electron is bound to an atom, its wavelength must fit into a small space like a standing wave on a string. - Allowed orbits are those orbits in which an electron constructively interferes with itself.
  • Not all orbits produce constructive interference.
  • Only certain orbits are allowed, meaning the orbits are quantized.
Quantization

Quantization

  • For a circular orbit, the electron waves must fit an integer number of times into the circumference of the orbit:
    • nλn=2πrnn\lambda_n = 2\pi r_n
  • Where λn is the electron’s wavelength and rn is the radius of that circular orbit.
Quantization 2

Quantization 2

  • Substituting for the de Broglie wavelength of an electron we have:
    • nhmeν=2πrnn\frac{h}{m_e \nu}=2\pi r_n
  • Substituting for the angular momentum L we can write:
    • L=meνrn=nh2π  (n=1,2,3...)L = m_e\nu r_n =n\frac{h}{2\pi} \;(n=1,2,3...)
  • So the angular momentum for electrons in orbit must be quantized.
Jump to other topics
1

Space, Time & Motion

2

The Particulate Nature of Matter

3

Wave Behaviour

4

Fields

4.1

Circular Motion

4.2

Newton's Law of Gravitation

4.3

Fields

4.4

Fields at Work

4.5

Electric Fields

4.6

Magnetic Effect of Electric Currents

4.7

Heating Effect of Currents

4.8

Electromagnetic Induction

4.9

Power Generation & Transmission

4.10

Capacitance

5

Nuclear & Quantum Physics

6

Measurements

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