5.1.1
Atomic Spectra
Absorption Spectra
Absorption Spectra
Electrons in atoms can only move between discrete energy levels. So an atom can only absorb or emit photons with particular frequencies (or wavelengths).


White light - continuous spectrum
White light - continuous spectrum
- White light contains all the colors in the visible part of the spectrum.
- When white light is passed through a prism or a diffraction grating, the colors are split up to produce a continuous spectrum.
- Continuous means there aren't any gaps or black lines.


Cool gas - absorption spectra
Cool gas - absorption spectra
- A cool gas means a gas containing atoms in their ground state.
- When white light is passed through a cool gas, electrons in the ground state of the atom absorb certain frequencies of light and become excited.
- Most frequencies of the white light are not absorbed because they do not correspond to the difference between two energy levels in the atom.


Absorption spectra 2
Absorption spectra 2
- If the light coming out of the cool gas is split by a prism (or diffraction grating), we see a continuous spectrum with black lines.
- These lines are called absorption lines.
- They are unique to each type of atom.
Emission Spectra
Emission Spectra
Electrons in atoms can only move between discrete energy levels. So an atom can only absorb or emit photons with particular frequencies (or wavelengths).


Excited gas
Excited gas
- An excited gas contains atoms in excited energy states.
- These excited atoms contain electrons in high energy levels.
- As these electrons de-excite and fall back to lower energy levels, photons are emitted.


Photon emission
Photon emission
- These photons carry away energy from the atoms.
- The amount of energy (and so what frequency) the photons have depends on the difference in energy levels in the atom.
- For every possible electron transition, there will be a unique frequency photon emitted.
- We see a series of bright lines when we pass the emitted light through a prism or diffraction grating.


Emission vs absorption
Emission vs absorption
- Compare the emission and absorption spectra produced by this gas.
- We can see that the emission lines exactly match the frequencies of the absorption lines.
- This is because the lines correspond to the same energy differences in the atoms. The same energy photons are either emitted or absorbed.
1Space, Time & Motion
1.1Motion
1.2Forces
1.3Momentum & Impulse
2The Particulate Nature of Matter
2.1Thermal Concepts
3Wave Behaviour
3.1Oscillations
3.2Travelling Waves
3.3Wave Characteristics
3.4Wave Behaviour
3.5Standing Waves
3.6Simple Harmonic Motion
3.7Single Slit Diffraction
3.8Interference
3.9Doppler Effect
4Fields
4.1Circular Motion
4.2Newton's Law of Gravitation
4.3Fields
4.4Fields at Work
4.5Electric Fields
4.6Magnetic Effect of Electric Currents
4.7Heating Effect of Currents
4.8Electromagnetic Induction
4.9Power Generation & Transmission
5Nuclear & Quantum Physics
5.1Discrete Energy & Radioactivity
5.2Nuclear Reactions
5.3The Interaction of Matter with Radiation
6Measurements
6.1Measurements & Errors
6.2Uncertainties & Errors
6.3Vectors & Scalars
Jump to other topics
1Space, Time & Motion
1.1Motion
1.2Forces
1.3Momentum & Impulse
2The Particulate Nature of Matter
2.1Thermal Concepts
3Wave Behaviour
3.1Oscillations
3.2Travelling Waves
3.3Wave Characteristics
3.4Wave Behaviour
3.5Standing Waves
3.6Simple Harmonic Motion
3.7Single Slit Diffraction
3.8Interference
3.9Doppler Effect
4Fields
4.1Circular Motion
4.2Newton's Law of Gravitation
4.3Fields
4.4Fields at Work
4.5Electric Fields
4.6Magnetic Effect of Electric Currents
4.7Heating Effect of Currents
4.8Electromagnetic Induction
4.9Power Generation & Transmission
5Nuclear & Quantum Physics
5.1Discrete Energy & Radioactivity
5.2Nuclear Reactions
5.3The Interaction of Matter with Radiation
6Measurements
6.1Measurements & Errors
6.2Uncertainties & Errors
6.3Vectors & Scalars
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