5.1.7

Radioactive Decay

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Radioactive Decay

When an object is radioactive it releases radioactive particles but as time passes the rate of particles decreases. This is called decay.

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Random decay

  • The decay of a radioactive substance is random and unpredictable.
  • To measure decay, we must look at the count rate over a long time to see if it decreases.
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Probability

  • The probability that a given nucleus will decay in a given time is proportional to the number of nuclei. The equation for calculating the rate of decay is:
    • The rate of decay of nuclei = decay constant x the number of nuclei
    • ΔNΔt=λN\frac{{\Delta}N}{{\Delta}t}=-{\lambda}N
      • λ{\lambda} is the decay constant.
      • NN is the number of nuclei.

The Exponential Law

The reduction in the rate of decay decreases according to an exponential pattern.

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Exponential decay

  • From the equation for the rate of decay, we can find an exponential relationship between the number of nuclei and time.
  • The equation for the rate of decay of nuclei is:
    • ΔNΔt=λN\frac{{\Delta}N}{{\Delta}t}=-{\lambda}N
  • The exponential relationship corresponding to this is:
    • N=N0eλtN={N_0}e^{-{\lambda}t}
      • N0{N_0} is the initial number of nuclei.
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Activity

  • The activity of a sample can be found by using the decay constant and the number of nuclei. The equation for activity is:
    • Activity = decay constant x number of nuclei
    • A=λNA={\lambda}N
  • The exponential relationship corresponding to the activity is:
    • A=A0eλtA={A_0}e^{-{\lambda}t}

Half-Life

Although each nuclear decay is random, with a large collection of nuclei, we can statistically predict how many will decay after a certain time.

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Time taken to halve

  • Half-life, T1/2, is the time taken:
    • For the number of radioactive nuclei in a sample to halve.
    • For the activity (the number of decays per second) to halve.
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Activity

  • The activity of a sample is directly proportional to the number of nuclei remaining:
    • Activity = decay constant, λ x number of nuclei remaining.
  • Activity is related to the half life:
    • λ=ln(2)T1/2=0.693T1/2λ =\frac{ \ln (2)}{T_{1/2}} = \frac{0.693}{T_{1/2}}
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Activity 2

  • By knowing the activity, we can infer how many nuclei are remaining.
  • Knowing the atomic mass of an isotope and the mass of a sample of isotope enables the number of nuclei and so the activity to be found.
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Example

  • Find the half-life of a sample of plutonium-239, which has a mass of 1200 g and an activity of 2.8 × 1012 Bq:
    • Number of moles of Pu-239 = 1200 ÷ 239 = 5.021.
    • Number of nuclei = number of moles × Avogadro’s constant = 3.02 × 1024.
    • λ = activity ÷ number of nuclei = 9.26 × 10-13.
    • So, half-life T1/2 = ln(2) ÷ λ = 7.5 × 1010 s.

Jump to other topics

1Space, Time & Motion

2The Particulate Nature of Matter

3Wave Behaviour

4Fields

4.1Circular Motion

4.2Newton's Law of Gravitation

4.3Fields

4.4Fields at Work

4.5Electric Fields

4.6Magnetic Effect of Electric Currents

4.7Heating Effect of Currents

4.8Electromagnetic Induction

4.9Power Generation & Transmission

4.10Capacitance

5Nuclear & Quantum Physics

6Measurements

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