2.1.7

Rate of Reaction 2

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Rate of Reaction - Key Factors

The main factors that affect the rate of chemical reactions are:

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Concentration of dissolved reactants

  • Increasing the concentration increases the frequency (number) of collisions. This increases the rate of reaction.
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Pressure of gas reactants

  • Increasing pressure is like increasing the concentration.
  • It increases the frequency (number) of collisions. This increases the rate of reaction (makes the reaction faster).
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Temperature

  • Increasing the temperature increases the frequency (number) of collisions.
  • Increasing the temperature increases the energy of reactant particles. This means that a greater proportion (more) of the particles will have more energy than the activation energy that is needed.
  • Together, these lead to more successful collisions. This increases the rate of reaction.
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Surface area of solid reactants

  • Increasing the surface area increases the frequency (number) of collisions. This increases the rate of reaction.
  • This is often done by breaking up solids into smaller lumps (e.g. powders).
  • This increase in surface area to volume ratio makes sure that more particles are exposed to attack.
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Catalysts

  • Catalysts are substances that increase the rate of a chemical reaction without being used up in the process.

Catalysts

Catalysts increase the rate of chemical reactions by lowering the activation energy. They do this by providing a different reaction pathway.

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Not used up

  • Catalysts are not used up during chemical reactions. This means that:
    • They can be reused indefinitely.
    • They are not found in chemical equations.
  • However, catalysts will often need cleaning or regenerating, which has knock-on effects for energy expenditure and environmental impact.
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Different catalysts

  • Different reactions need different catalysts:
    • Iron is used in the process that makes ammonia.
    • Platinum and palladium are used in catalytic converters in cars.
    • Enzymes catalyse reactions in biological systems.
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Powders

  • Catalysts often come as powders, pellets or fine gauzes because these types of substance have particularly high surface areas.

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