Graphene & Fullerene

Chemistry: Cambridge International A Level, topic 1.4.9

Graphene

Graphene is an allotrope (form) of carbon. It has the following properties:

Conducts electricity

Conducts electricity

  • Each carbon atom has a delocalised electron.
  • Graphene is a single layer of graphite so it also conducts electricity because of the carbon atoms’ delocalised electrons.
Light but strong

Light but strong

  • Graphene is 1 atom (1 layer) thick.
  • This means that it is almost a 2-dimensional structure. This makes graphene very light.
  • However, the strong covalent bonds between carbon atoms mean that it is also very strong.
Uses

Uses

  • Graphene has lots of uses in electronics and composite materials (materials that have things added to make them more useful).
  • It increases a material’s strength without adding much weight.
  • It can be used in solar panels, batteries and much more.

Fullerenes

Fullerenes are molecules of carbon atoms that have hollow shapes. Their structure is mainly based on hexagonal (6-sided) rings of carbon atoms, but can also contain pentagonal (5-sided) and heptagonal (7-sided) rings.

Spherical fullerenes - buckminsterfullerene

Spherical fullerenes - buckminsterfullerene

  • The 1st fullerene to be discovered - buckminsterfullerene - is spherical.
  • It has the formula C60.
  • It is technically a simple molecule because of its fixed size.
Spherical fullerenes - uses

Spherical fullerenes - uses

  • Generally speaking, spherical fullerenes come in a wide range of sizes, and their common uses include:
  • Catalysts.
  • Lubricants.
  • Delivering drugs into the body.
Cylindrical fullerenes - shape

Cylindrical fullerenes - shape

  • Carbon nanotubes are cylindrical fullerenes.
  • They are often called molecular wires because they have a tiny diameter but can be incredibly long.
Cylindrical fullerenes - strength

Cylindrical fullerenes - strength

  • Because of the strong covalent bonds between carbon atoms, nanotubes are exceptionally strong for their size.
Cylindrical fullerenes - uses

Cylindrical fullerenes - uses

  • The strength and electrical conductivity of nanotubes make them useful:
  • In electronics.
  • In nanotechnology.
  • For strengthening materials (e.g. tennis racket frames).

Test yourself on Graphene & Fullerene

  • Which of graphene and graphite is an electrical conductor?

  • Which is a harder compound?

  • Which explains why graphene is used in composite materials?

  • Why is graphene very light?

  • Name the carbon ring shapes found in fullerene structures

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