Magnitude of the Equilibrium Constant

Chemistry: IB Diploma Higher Level, topic 5.6.2

Magnitude of the Equilibrium Constant

The equilibrium constant for a reaction tells you the relative position of the reversible reaction at equilibrium.

Large equilibrium constants

Large equilibrium constants

  • A reaction with a large equilibrium constant (K) will be at equilibrium when most of the reactant has been converted into the product.
    • An equilibrium constant greater than one indicates that the forward reaction dominates.
Small equilibrium constants

Small equilibrium constants

  • A reaction with a small equilibrium constant (K) will be at equilibrium when very little of the reactant has been converted into the product.
  • An equilibrium constant less than one indicates that the backward reaction dominates.
K does NOT affect the rate

K does NOT affect the rate

  • The size of the equilibrium constant (K) does NOT show how fast or slow equilibrium will be reached.
  • Some equilibria are reached so quickly that they are almost instant.
  • Some equilibria are reached so slowly that it is very hard to see any change over the course of days or years.

Test yourself on Magnitude of the Equilibrium Constant

  • If Kc is greater than one, what does it indicate?

  • When does the backward reaction dominate?

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