Pure Substances

Chemistry: IB Diploma Higher Level, topic 1.6.2

Pure Substances

Matter can be classified into several categories. Two broad categories are mixtures and pure substances. A pure substance has a constant composition.

What are pure substances?

What are pure substances?

  • All specimens of a pure substance have exactly the same makeup and properties.
  • Any sample of sucrose (table sugar) consists of 42.1% carbon, 6.5% hydrogen, and 51.4% oxygen by mass.
  • Any sample of sucrose also has the same physical properties, such as melting point, color, and sweetness, regardless of the source from which it is isolated.
Pure substances - elements

Pure substances - elements

  • Pure substances may be divided into two classes: elements and compounds.
  • Pure substances that cannot be broken down into simpler substances by chemical changes are called elements.
  • Iron, silver, gold, aluminum, sulfur, oxygen, and copper are familiar examples of the more than 100 known elements.
Compounds

Compounds

  • Pure substances that can be broken down by chemical changes are called compounds.
  • This breakdown may produce either elements or other compounds, or both.
  • Mercury(II) oxide, an orange, crystalline solid, can be broken down by heat into the elements mercury and oxygen.
Compounds - 2

Compounds - 2

  • The properties of combined elements are different from those in the free, or uncombined, state.
  • For example, free sodium is an element that is a soft, shiny, metallic solid. Free chlorine is an element that is a yellow-green gas.
  • Sodium and chlorine combine to form sodium chloride (table salt), a compound that is a white, crystalline solid.

Effects of Impurities in a Sample

Chemically pure substances have exact and specific melting and boiling points. Adding impurities affects these values.

Decreases melting point

Increases boiling point

Reduces range of temperatures

  • Reduces the range of temperatures at which the sample melts or boils.

Test yourself on Pure Substances

  • More impurities in a sample will...

  • What does it mean if a solid melts over a range of temperatures, instead of at one exact point?

  • How do impurities affect the melting and boiling points of samples?

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