Dipole-Dipole Interactions

Chemistry: IB Diploma Higher Level, topic 2.8.3

Permanent Dipole-Dipole Interactions

Permanent dipole-dipole interactions exist between two permanently polar molecules.

Permanent dipoles

Permanent dipoles

  • Permanent dipoles have a δ- on one side and a δ+ on the other.
  • The δ+ of one molecule will attract the δ- of another molecule.
  • This means that the molecules will line up throughout a liquid or solid in this fashion.
  • Permanent dipole-dipole forces are the second strongest molecular interaction.
Polar molecules

Polar molecules

  • Permanent dipole-dipole interactions are only possible in molecules that contain a permanent dipole.
  • So they are only found between polar molecules.

Test yourself on Dipole-Dipole Interactions

  • A permanent dipole is labeled by which of the following?

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