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Chemistry: AQA A Level, topic 5.6.2

Testing for Alkenes

We can test a solution to see if the alkene function group is present.

The test

The test

  • Add bromine water to the solution.
  • If an alkene is present, the solution will lose its orange colour and become colourless.
  • If an alkene is not present, it will NOT decolourise and the solution remains orange.
How the test works

How the test works

  • The test works because:
  • If the alkene is present, it can undergo an addition reaction with the bromine.
  • This removes the bromine (in the bromine water) and forms a halogenoalkane - so the colour is lost.
Bromine water

Bromine water

  • As a quick note, bromine water is just water with a small amount of bromine dissolved in it.
  • Bromine water is what colours the solution orange until it has reacted with the alkene.

Testing for Carboxylic Acids

We can test to see if a carboxylic acid is present in a solution.

The test

The test

  • Firstly we must react the carboxylic acid with sodium carbonates.
  • The reaction with the carbonate ions should form a salt + CO2 + H2O
  • We can then test for the CO2 produced using limewater.
Limewater

Limewater

  • Limewater is a clear solution but it is turned cloudy if CO2 is present.
  • This means we must pump the gas, produced from the reaction between the sample and the carbonate, into limewater.
    • If limewater turns cloudy: carboxylic acid is present in the initial solution.
    • If limewater stays clear: carboxylic acid is NOT present in the initial solution.

Test yourself on Reactions 2

  • A solution does NOT contain an alkene. What will happen if bromine water is added?

  • Which of the following is NOT needed to test for carboxylic acids?

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