13.1.5
Energy Levels & Photon Emission
Energy Levels in Atoms
Energy Levels in Atoms
Electrons in atoms must occupy a discrete energy level.
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Energy levels
Energy levels
- Electrons do not float around randomly in atoms.
- They can only be found at set energy levels.
- Each energy level is given a 'quantum number'.
- The ground state is the lowest energy level. The ground state has n = 1.
- The higher the energy level, the larger its quantum number, n.


Transitions between energy levels
Transitions between energy levels
- An electron can transition between energy levels by absorbing or emitting a photon of a specific frequency.
- If an electron emits a photon, it will drop in energy level.
- If an electron absorbs a photon, it will rise to a higher level.
- In both cases, the photon must have energy exactly equal to the energy difference between the levels.


Equation
Equation
- The movement of electrons between energy levels can be represented in the equation:
- This shows that the energy difference between levels one and two is equal to the energy of the emitted (or absorbed) photon.


Excitation and ionisation
Excitation and ionisation
- If an electron absorbs a photon and jumps up an energy level, we say it has been excited.
- If an electron absorbs a photon that is so energetic it is knocked out of the atom altogether, the electron has been ionised.
Absorption Spectra
Absorption Spectra
Electrons in atoms can only move between discrete energy levels. So an atom can only absorb or emit photons with particular frequencies (or wavelengths).


White light - continuous spectrum
White light - continuous spectrum
- White light contains all the colours in the visible part of the spectrum.
- When white light is passed through a prism or a diffraction grating, the colours are split up to produce a continuous spectrum.
- Continuous means there aren't any gaps or black lines.


Cool gas - absorption spectra
Cool gas - absorption spectra
- A cool gas means a gas containing atoms in their ground state.
- When white light is passed through a cool gas, electrons in the ground state of the atom absorb certain frequencies of light and become excited.
- Most frequencies of the white light are not absorbed because they do not correspond to the difference between two energy levels in the atom.


Absorption spectra 2
Absorption spectra 2
- If the light coming out of the cool gas is split by a prism (or diffraction grating), we see a continuous spectrum with black lines.
- These lines are called absorption lines.
- They are unique to each type of atom.
Emission Spectra
Emission Spectra
Electrons in atoms can only move between discrete energy levels. So an atom can only absorb or emit photons with particular frequencies (or wavelengths).


Excited gas
Excited gas
- An excited gas contains atoms in excited energy states.
- These excited atoms contain electrons in high energy levels.
- As these electrons de-excite and fall back to lower energy levels, photons are emitted.


Photon emission
Photon emission
- These photons carry away energy from the atoms.
- The amount of energy (and so what frequency) the photons have depends on the difference in energy levels in the atom.
- For every possible electron transition, there will be a unique frequency photon emitted.
- We see a series of bright lines when we pass the emitted light through a prism or diffraction grating.


Emission vs absorption
Emission vs absorption
- Compare the emission and absorption spectra produced by this gas.
- We can see that the emission lines exactly match the frequencies of the absorption lines.
- This is because the lines correspond to the same energy differences in the atoms. The same energy photons are either emitted or absorbed.
1Physical Quantities & Units
2Measurement Techniques
3Kinematics
4Dynamics
4.1Momentum & Newton's Laws of Motion
4.2Non-Uniform Motion
4.3Linear Momentum & Conservation
4.4Force, Density & Pressure
4.4.1Fields
4.4.2Force in Uniform Fields
4.4.3Friction
4.4.4Buoyancy
4.4.5Terminal Speed
4.4.6End of Topic Test - Acceleration Due to Gravity
4.4.7Centre of Mass
4.4.8Forces & Equilibrium
4.4.9End of Topic Test - Scalars & Vectors
4.4.10Moments
4.4.11End of Topic Test - Moments & Centre of Mass
4.4.12Density
4.4.13Pressure
4.5Work, Energy & Power
5Gravitational Fields
5.1Gravitational Fields (A2 only)
6Deformation of Solids
7Thermal Physics
7.1Thermal Physics
7.1.1Temperature
7.1.2Measuring Temperature
7.1.3Ideal Gas Law
7.1.4Ideal Gases
7.1.5Boyle's Law & Charles' Law
7.1.6Molecular Kinetic Theory Model
7.1.7Molecular Kinetic Theory Model 2
7.1.8Thermal Energy Transfer
7.1.9Thermal Energy Transfer Experiments
7.1.10End of Topic Test - Thermal Energy & Ideal Gases
7.1.11First Law of Thermodynamics
8Oscillations
8.1Simple Harmonic Motion
8.2Waves
8.2.1Progressive Waves
8.2.2Intensity of Waves
8.2.3Wave Speed & Phase Difference
8.2.4Longitudinal & Transverse Waves
8.2.5End of Topic Test - Progressive Waves
8.2.6Electromagnetic Waves
8.2.7Doppler Effect
8.2.8Sound Waves
8.2.9Measuring Sound Waves
8.2.10End of Topic Test - Waves
8.2.11Ultrasound Imaging
8.2.12Ultrasound Imaging 2
9Communication
9.1Communication Channels
9.2Digital Communication
10Electric Fields
10.1Electric Fields
11Current Electricity
11.1Current Electricity
11.1.1Basics of Electricity
11.1.2Mean Drift Velocity
11.1.3Current-Voltage Characteristics
11.1.4End of Topic Test - Basics of Electricity
11.1.5Resistivity
11.1.6End of Topic Test - Resistivity & Superconductors
11.1.7Power and Conservation
11.1.8Microphones
11.1.9Components
11.1.10Relays
11.1.11Strain Gauges
12Magnetic Fields
12.1Magnetic Fields
13Modern Physics
13.1Quantum Physics
13.1.1The Photoelectric Effect
13.1.2The Photoelectric Effect Explanation
13.1.3End of Topic Test - The Photoelectric Effect
13.1.4Collisions of Electrons with Atoms
13.1.5Energy Levels & Photon Emission
13.1.6Wave-Particle Duality
13.1.7End of Topic Test - Absorption & Emission
13.1.8Band Theory
13.1.9Diagnostic X-Rays
13.1.10X-Ray Image Processing
13.1.11Absorption of X-Rays
13.1.12CT Scanners
13.2Nuclear Physics
13.2.1Rutherford Scattering
13.2.2Atomic Model
13.2.3Isotopes
13.2.4Stable & Unstable Nuclei
13.2.5A-A* (AO3/4) - Stable & Unstable Nuclei
13.2.6Alpha & Beta Radiation
13.2.7Gamma Radiation
13.2.8Particles, Antiparticles & Photons
13.2.9Quarks & Antiquarks
13.2.10Particle Interactions
13.2.11Radioactive Decay
13.2.12Half Life
13.2.13End of Topic Test - Radioactivity
13.2.14Nuclear Instability
13.2.15Mass & Energy
13.2.16Binding Energy
13.2.17A-A* (AO3/4) - Nuclear Fusion
Jump to other topics
1Physical Quantities & Units
2Measurement Techniques
3Kinematics
4Dynamics
4.1Momentum & Newton's Laws of Motion
4.2Non-Uniform Motion
4.3Linear Momentum & Conservation
4.4Force, Density & Pressure
4.4.1Fields
4.4.2Force in Uniform Fields
4.4.3Friction
4.4.4Buoyancy
4.4.5Terminal Speed
4.4.6End of Topic Test - Acceleration Due to Gravity
4.4.7Centre of Mass
4.4.8Forces & Equilibrium
4.4.9End of Topic Test - Scalars & Vectors
4.4.10Moments
4.4.11End of Topic Test - Moments & Centre of Mass
4.4.12Density
4.4.13Pressure
4.5Work, Energy & Power
5Gravitational Fields
5.1Gravitational Fields (A2 only)
6Deformation of Solids
7Thermal Physics
7.1Thermal Physics
7.1.1Temperature
7.1.2Measuring Temperature
7.1.3Ideal Gas Law
7.1.4Ideal Gases
7.1.5Boyle's Law & Charles' Law
7.1.6Molecular Kinetic Theory Model
7.1.7Molecular Kinetic Theory Model 2
7.1.8Thermal Energy Transfer
7.1.9Thermal Energy Transfer Experiments
7.1.10End of Topic Test - Thermal Energy & Ideal Gases
7.1.11First Law of Thermodynamics
8Oscillations
8.1Simple Harmonic Motion
8.2Waves
8.2.1Progressive Waves
8.2.2Intensity of Waves
8.2.3Wave Speed & Phase Difference
8.2.4Longitudinal & Transverse Waves
8.2.5End of Topic Test - Progressive Waves
8.2.6Electromagnetic Waves
8.2.7Doppler Effect
8.2.8Sound Waves
8.2.9Measuring Sound Waves
8.2.10End of Topic Test - Waves
8.2.11Ultrasound Imaging
8.2.12Ultrasound Imaging 2
9Communication
9.1Communication Channels
9.2Digital Communication
10Electric Fields
10.1Electric Fields
11Current Electricity
11.1Current Electricity
11.1.1Basics of Electricity
11.1.2Mean Drift Velocity
11.1.3Current-Voltage Characteristics
11.1.4End of Topic Test - Basics of Electricity
11.1.5Resistivity
11.1.6End of Topic Test - Resistivity & Superconductors
11.1.7Power and Conservation
11.1.8Microphones
11.1.9Components
11.1.10Relays
11.1.11Strain Gauges
12Magnetic Fields
12.1Magnetic Fields
13Modern Physics
13.1Quantum Physics
13.1.1The Photoelectric Effect
13.1.2The Photoelectric Effect Explanation
13.1.3End of Topic Test - The Photoelectric Effect
13.1.4Collisions of Electrons with Atoms
13.1.5Energy Levels & Photon Emission
13.1.6Wave-Particle Duality
13.1.7End of Topic Test - Absorption & Emission
13.1.8Band Theory
13.1.9Diagnostic X-Rays
13.1.10X-Ray Image Processing
13.1.11Absorption of X-Rays
13.1.12CT Scanners
13.2Nuclear Physics
13.2.1Rutherford Scattering
13.2.2Atomic Model
13.2.3Isotopes
13.2.4Stable & Unstable Nuclei
13.2.5A-A* (AO3/4) - Stable & Unstable Nuclei
13.2.6Alpha & Beta Radiation
13.2.7Gamma Radiation
13.2.8Particles, Antiparticles & Photons
13.2.9Quarks & Antiquarks
13.2.10Particle Interactions
13.2.11Radioactive Decay
13.2.12Half Life
13.2.13End of Topic Test - Radioactivity
13.2.14Nuclear Instability
13.2.15Mass & Energy
13.2.16Binding Energy
13.2.17A-A* (AO3/4) - Nuclear Fusion
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