13.1.4
Collisions of Electrons with Atoms
Ionisation and Excitation
Ionisation and Excitation
Both electrons being removed from an atom and the movement of electrons within energy levels in the atom explain commonly observed phenomena.


Ionisation
Ionisation
- To ionise an atom means to remove or add electrons to an atom.
- Ionisation in the context of quantum phenomena almost always means the removal of electrons completely from the atom.
- The energy needed for an electron to go from the ground state to being completely removed is called the ionisation energy.


Excitation
Excitation
- Electrons can also be made to move from one energy level to the other.
- To do this, the electron needs exactly the energy difference between energy levels.
- One way to do this is for a photon to interact with the electron.
- The electron will absorb all the energy of the photon.


Excitation 2
Excitation 2
- If the energy of the photon is exactly the energy difference between the energy levels, the electron will move up the energy levels.
- When an electron has moved up energy levels we called the electron "excited".
- The process of making the electron move up energy levels is called "excitation".
Fluorescent Tubes
Fluorescent Tubes
It is important to understand how fluorescent tubes work.


Constituents of the tube
Constituents of the tube
- A fluorescent tube has mercury vapour inside it.
- A fluorescent tube is coated on the inside with phosphor.
- There are free electrons in the fluorescent tube.
- A high voltage will accelerate these free electrons.


Excitation of electrons
Excitation of electrons
- The high-energy free electrons then ionise the mercury vapour.
- This means that there are more free electrons than previously.
- The free electrons then excite electrons in the mercury atoms.


Release of photons
Release of photons
- The excited electrons then move back to their ground state.
- When they do so, they release the excess energy in the form of photons.
- These photons are high-frequency, high-energy, ultraviolet photons.


Absorption of high-energy photons
Absorption of high-energy photons
- The ultra-violet photons then collide with the phosphor coating on the inside of the tube.
- The electrons in the phosphor are now excited.


Release of visible light photons
Release of visible light photons
- The excited electrons then eventually move back to their ground state. When they do so, they release the excess energy in the form of photons.
- These photons have a frequency in the visible range.
The Electron Volt
The Electron Volt
When dealing with energy levels of individual atoms, the SI unit of energy (the Joule, J) is far too big. So we need to define a more appropriate unit of energy, the electron volt, eV.


Definition of electron volt
Definition of electron volt
- The electron volt is defined as the energy given to a fundamental charge, e, accelerated through a potential difference of 1 Volt.


Conversion
Conversion
- To convert between J and eV, simply multiply or divide by the charge of the electron, e = 1.6×10-19.
- 1 eV = 1.6 ×10-19 J


Example - hydrogen
Example - hydrogen
- Let's say the energy of an electron in a hydrogen atom is 13.6 eV.
- To find this in Joules, use the equation shown previously:
- 13.6 eV = 13.6 × 1.6 ×10-19 J
- 13.6 eV = 2.18 ×10-18 J (3 s.f.)
1Physical Quantities & Units
2Measurement Techniques
3Kinematics
4Dynamics
4.1Momentum & Newton's Laws of Motion
4.2Non-Uniform Motion
4.3Linear Momentum & Conservation
4.4Force, Density & Pressure
4.4.1Fields
4.4.2Force in Uniform Fields
4.4.3Friction
4.4.4Buoyancy
4.4.5Terminal Speed
4.4.6End of Topic Test - Acceleration Due to Gravity
4.4.7Centre of Mass
4.4.8Forces & Equilibrium
4.4.9End of Topic Test - Scalars & Vectors
4.4.10Moments
4.4.11End of Topic Test - Moments & Centre of Mass
4.4.12Density
4.4.13Pressure
4.5Work, Energy & Power
5Gravitational Fields
5.1Gravitational Fields (A2 only)
6Deformation of Solids
7Thermal Physics
7.1Thermal Physics
7.1.1Temperature
7.1.2Measuring Temperature
7.1.3Ideal Gas Law
7.1.4Ideal Gases
7.1.5Boyle's Law & Charles' Law
7.1.6Molecular Kinetic Theory Model
7.1.7Molecular Kinetic Theory Model 2
7.1.8Thermal Energy Transfer
7.1.9Thermal Energy Transfer Experiments
7.1.10End of Topic Test - Thermal Energy & Ideal Gases
7.1.11First Law of Thermodynamics
8Oscillations
8.1Simple Harmonic Motion
8.2Waves
8.2.1Progressive Waves
8.2.2Intensity of Waves
8.2.3Wave Speed & Phase Difference
8.2.4Longitudinal & Transverse Waves
8.2.5End of Topic Test - Progressive Waves
8.2.6Electromagnetic Waves
8.2.7Doppler Effect
8.2.8Sound Waves
8.2.9Measuring Sound Waves
8.2.10End of Topic Test - Waves
8.2.11Ultrasound Imaging
8.2.12Ultrasound Imaging 2
9Communication
9.1Communication Channels
9.2Digital Communication
10Electric Fields
10.1Electric Fields
11Current Electricity
11.1Current Electricity
11.1.1Basics of Electricity
11.1.2Mean Drift Velocity
11.1.3Current-Voltage Characteristics
11.1.4End of Topic Test - Basics of Electricity
11.1.5Resistivity
11.1.6End of Topic Test - Resistivity & Superconductors
11.1.7Power and Conservation
11.1.8Microphones
11.1.9Components
11.1.10Relays
11.1.11Strain Gauges
12Magnetic Fields
12.1Magnetic Fields
13Modern Physics
13.1Quantum Physics
13.1.1The Photoelectric Effect
13.1.2The Photoelectric Effect Explanation
13.1.3End of Topic Test - The Photoelectric Effect
13.1.4Collisions of Electrons with Atoms
13.1.5Energy Levels & Photon Emission
13.1.6Wave-Particle Duality
13.1.7End of Topic Test - Absorption & Emission
13.1.8Band Theory
13.1.9Diagnostic X-Rays
13.1.10X-Ray Image Processing
13.1.11Absorption of X-Rays
13.1.12CT Scanners
13.2Nuclear Physics
13.2.1Rutherford Scattering
13.2.2Atomic Model
13.2.3Isotopes
13.2.4Stable & Unstable Nuclei
13.2.5A-A* (AO3/4) - Stable & Unstable Nuclei
13.2.6Alpha & Beta Radiation
13.2.7Gamma Radiation
13.2.8Particles, Antiparticles & Photons
13.2.9Quarks & Antiquarks
13.2.10Particle Interactions
13.2.11Radioactive Decay
13.2.12Half Life
13.2.13End of Topic Test - Radioactivity
13.2.14Nuclear Instability
13.2.15Mass & Energy
13.2.16Binding Energy
13.2.17A-A* (AO3/4) - Nuclear Fusion
Jump to other topics
1Physical Quantities & Units
2Measurement Techniques
3Kinematics
4Dynamics
4.1Momentum & Newton's Laws of Motion
4.2Non-Uniform Motion
4.3Linear Momentum & Conservation
4.4Force, Density & Pressure
4.4.1Fields
4.4.2Force in Uniform Fields
4.4.3Friction
4.4.4Buoyancy
4.4.5Terminal Speed
4.4.6End of Topic Test - Acceleration Due to Gravity
4.4.7Centre of Mass
4.4.8Forces & Equilibrium
4.4.9End of Topic Test - Scalars & Vectors
4.4.10Moments
4.4.11End of Topic Test - Moments & Centre of Mass
4.4.12Density
4.4.13Pressure
4.5Work, Energy & Power
5Gravitational Fields
5.1Gravitational Fields (A2 only)
6Deformation of Solids
7Thermal Physics
7.1Thermal Physics
7.1.1Temperature
7.1.2Measuring Temperature
7.1.3Ideal Gas Law
7.1.4Ideal Gases
7.1.5Boyle's Law & Charles' Law
7.1.6Molecular Kinetic Theory Model
7.1.7Molecular Kinetic Theory Model 2
7.1.8Thermal Energy Transfer
7.1.9Thermal Energy Transfer Experiments
7.1.10End of Topic Test - Thermal Energy & Ideal Gases
7.1.11First Law of Thermodynamics
8Oscillations
8.1Simple Harmonic Motion
8.2Waves
8.2.1Progressive Waves
8.2.2Intensity of Waves
8.2.3Wave Speed & Phase Difference
8.2.4Longitudinal & Transverse Waves
8.2.5End of Topic Test - Progressive Waves
8.2.6Electromagnetic Waves
8.2.7Doppler Effect
8.2.8Sound Waves
8.2.9Measuring Sound Waves
8.2.10End of Topic Test - Waves
8.2.11Ultrasound Imaging
8.2.12Ultrasound Imaging 2
9Communication
9.1Communication Channels
9.2Digital Communication
10Electric Fields
10.1Electric Fields
11Current Electricity
11.1Current Electricity
11.1.1Basics of Electricity
11.1.2Mean Drift Velocity
11.1.3Current-Voltage Characteristics
11.1.4End of Topic Test - Basics of Electricity
11.1.5Resistivity
11.1.6End of Topic Test - Resistivity & Superconductors
11.1.7Power and Conservation
11.1.8Microphones
11.1.9Components
11.1.10Relays
11.1.11Strain Gauges
12Magnetic Fields
12.1Magnetic Fields
13Modern Physics
13.1Quantum Physics
13.1.1The Photoelectric Effect
13.1.2The Photoelectric Effect Explanation
13.1.3End of Topic Test - The Photoelectric Effect
13.1.4Collisions of Electrons with Atoms
13.1.5Energy Levels & Photon Emission
13.1.6Wave-Particle Duality
13.1.7End of Topic Test - Absorption & Emission
13.1.8Band Theory
13.1.9Diagnostic X-Rays
13.1.10X-Ray Image Processing
13.1.11Absorption of X-Rays
13.1.12CT Scanners
13.2Nuclear Physics
13.2.1Rutherford Scattering
13.2.2Atomic Model
13.2.3Isotopes
13.2.4Stable & Unstable Nuclei
13.2.5A-A* (AO3/4) - Stable & Unstable Nuclei
13.2.6Alpha & Beta Radiation
13.2.7Gamma Radiation
13.2.8Particles, Antiparticles & Photons
13.2.9Quarks & Antiquarks
13.2.10Particle Interactions
13.2.11Radioactive Decay
13.2.12Half Life
13.2.13End of Topic Test - Radioactivity
13.2.14Nuclear Instability
13.2.15Mass & Energy
13.2.16Binding Energy
13.2.17A-A* (AO3/4) - Nuclear Fusion
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