7.1.3

Electrolysis - Aqueous Solutions

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Electrolysis of Aqueous Solutions

The products of the electrolysis of aqueous solutions are difficult to predict because the water molecules in the solution split up to give hydrogen (H+) and hydroxide (OH-) ions.

At the anode (positive electrode)

At the anode (positive electrode)

  • What is formed at the anode depends on if there are halide ions present:
    • If there are halide ions present, the respective halogen forms.
    • If there are no halide ions, oxygen forms.
At the cathode (negative electrode)

At the cathode (negative electrode)

  • What is formed at the cathode depends on the reactivity of the metal:
    • Hydrogen is produced if the metal is higher than hydrogen in the reactivity series.
    • The metal is produced if the metal is lower than hydrogen in the reactivity series.
Jump to other topics
1

States of Matter

2

Elements, Compounds & Mixtures

3

Atomic Structure

4

The Periodic Table

5

Chemical Formulae, Equations & Calculations

6

Bonding

7

Electrolysis

8

Groups of the Periodic Table

9

The Atmosphere

10

Reactivity Series

11

Metal Extraction

12

Acids & Alkalis

13

Chemical Tests

14

Physical Chemistry

15

Organic Chemistry

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